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Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using palladium catalyst supported on mesoporous graphitic carbon nitride
Chen Jiayi; Ge Yao; Guo Yuanyuan; Chen Jinzhu
2018
Source PublicationJournal of Energy Chemistry
ISSN2095-4956
Volume27Issue:1Pages:283
AbstractSelective hydrogenation of biomass-derived 5-hydroxymethylfurfural (HMF) to 2,5-dihydroxymethyl-tetrahydrofuran (DHMTHF) with 96% selectivity and a complete HMF conversion is obtained over palladium catalyst supported on mesoporous graphitic carbon nitride (Pd 3 N 4 ) under pressured hydrogen atmosphere in aqueous media. The excellent catalytic performance of Pd 3 N 4 is attributed to hydrogen bonding-related competitive interactions between reactant HMF and “intermediate” 2,5-dihydroxymethylfuran (DHMF) with the support mpg-C 3 N 4 , which leads to a deep hydrogenation of DHMF to DHMTHF.
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/21374
Collection中国科学院广州能源研究所
Affiliation中国科学院广州能源研究所
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Chen Jiayi,Ge Yao,Guo Yuanyuan,et al. Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using palladium catalyst supported on mesoporous graphitic carbon nitride[J]. Journal of Energy Chemistry,2018,27(1):283.
APA Chen Jiayi,Ge Yao,Guo Yuanyuan,&Chen Jinzhu.(2018).Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using palladium catalyst supported on mesoporous graphitic carbon nitride.Journal of Energy Chemistry,27(1),283.
MLA Chen Jiayi,et al."Selective hydrogenation of biomass-derived 5-hydroxymethylfurfural using palladium catalyst supported on mesoporous graphitic carbon nitride".Journal of Energy Chemistry 27.1(2018):283.
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