Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst | |
Sun, Fei1,2; Chen, Lungang1; Weng, Yujing1; Wang, Tiejun1; Qiu, Songbai1; Li, Quanxin3; Wang, Chenguang1; Zhang, Qi1; Ma, Longlong1 | |
2017-08-01 | |
发表期刊 | CATALYSIS COMMUNICATIONS |
卷号 | 99页码:30-33 |
摘要 | The hydrodeoxygenation (HDO) of sorbitol in aqueous medium was performed over CNT supported Ru-Mo bimetallic catalyst. Compared with Ru-Mo/AC, Ru-Mo/CNT showed higher yield and selectivity towards C5/C6 alkanes due to the higher relative rate of C-O vs. C-C bond cleavage of sorbitol. Based on TEM, XPS and H-2-TPR characterizations, the role of CNT in HDO reaction was studied to clarify the likely reasons for the selective C-O vs. C-C bond cleavage. It is suggested that an increase concentration of MoOx (x < 3) species and a smaller metal particle size in the Ru-Mo/CNT catalyst are key factors for the improvement of HDO performance. |
文章类型 | Article |
关键词 | Biomass Hydrodeoxygenation Carbon Nanotubes Hydrocarbon Fuels |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1016/j.catcom.2017.05.014 |
研究领域[WOS] | Chemistry |
关键词[WOS] | CARBON NANOTUBES ; PHASE HYDRODEOXYGENATION ; LIGNOCELLULOSIC BIOMASS ; EFFICIENT CATALYSTS ; PROPANOIC ACID ; PARTICLE-SIZE ; CONVERSION ; ALKANES ; SORBITOL ; NANOPARTICLES |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(51476176 ; Key Project of National Natural Science Foundation of China(51536009) ; STS Program of Chinese Academy of Sciences(KFJ-EW-STS-138) ; Science and Technology Program of Guangdong Province(2014A010106022) ; 5161101344) |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000405973200007 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/14178 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China 3.Univ Sci & Technol China, Sch Chem & Mat Sci, Hefei 230000, Anhui, Peoples R China |
推荐引用方式 GB/T 7714 | Sun, Fei,Chen, Lungang,Weng, Yujing,et al. Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst[J]. CATALYSIS COMMUNICATIONS,2017,99:30-33. |
APA | Sun, Fei.,Chen, Lungang.,Weng, Yujing.,Wang, Tiejun.,Qiu, Songbai.,...&Ma, Longlong.(2017).Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst.CATALYSIS COMMUNICATIONS,99,30-33. |
MLA | Sun, Fei,et al."Transformation of biomass polyol into hydrocarbon fuels in aqueous medium over Ru-Mo/CNT catalyst".CATALYSIS COMMUNICATIONS 99(2017):30-33. |
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