Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural | |
Zhong, Jiawei1,2; Guo, Yuanyuan1; Chen, Jinzhu1
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| 2017 | |
| Source Publication | JOURNAL OF ENERGY CHEMISTRY
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| Volume | 26Issue:1Pages:147-154 |
| Abstract | A serial of protonated and layered transition metal oxides, including layered HTaWO6, HNbMoO6 as well as HNbWO6, were synthesized by solid-state reaction and ion-exchange. The layered HTaWO6 has been systematically studied as a solid acid to realize the dehydration of fructose to 5-hydroxymethylfurfural (HMF). The transition metal oxide samples were characterized with ICP-OES, EDS, XRD, XPS, SEM, TGA, FT-IR, N-2 adsorption-desorption and NH3-TPD. The influential factors such as reaction temperature, reaction time, solvent, catalyst amount and substrate concentration were deeply investigated. The optimized fructose conversion rate of 99% with HMF yield of 67% were achieved after 30 min at 140 degrees C in dimethylsulfoxide. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved. |
| Subtype | Article |
| Keyword | Biomass Dehydration 5-hydroxymethylfurfural Layered Transition Metal Oxide Solid Acid |
| WOS Headings | Science & Technology ; Physical Sciences ; Technology |
| DOI | 10.1016/j.jechem.2016.09.010 |
| WOS Subject Extended | Chemistry ; Energy & Fuels ; Engineering |
| WOS Keyword | CATALYTIC DEHYDRATION ; LEVULINIC ACID ; ION-EXCHANGE ; NIOBIC ACID ; CONVERSION ; NANOSHEETS ; HTAWO6 ; DERIVATIVES ; CHEMICALS ; GLUCOSE |
| Indexed By | SCI |
| Language | 英语 |
| Funding Organization | National Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010) |
| WOS Subject | Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000401302600019 |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/14123 |
| Collection | 中国科学院广州能源研究所 |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Zhong, Jiawei,Guo, Yuanyuan,Chen, Jinzhu. Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(1):147-154. |
| APA | Zhong, Jiawei,Guo, Yuanyuan,&Chen, Jinzhu.(2017).Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural.JOURNAL OF ENERGY CHEMISTRY,26(1),147-154. |
| MLA | Zhong, Jiawei,et al."Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural".JOURNAL OF ENERGY CHEMISTRY 26.1(2017):147-154. |
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