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Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural
Zhong, Jiawei1,2; Guo, Yuanyuan1; Chen, Jinzhu1
2017
Source PublicationJOURNAL OF ENERGY CHEMISTRY
Volume26Issue:1Pages:147-154
AbstractA serial of protonated and layered transition metal oxides, including layered HTaWO6, HNbMoO6 as well as HNbWO6, were synthesized by solid-state reaction and ion-exchange. The layered HTaWO6 has been systematically studied as a solid acid to realize the dehydration of fructose to 5-hydroxymethylfurfural (HMF). The transition metal oxide samples were characterized with ICP-OES, EDS, XRD, XPS, SEM, TGA, FT-IR, N-2 adsorption-desorption and NH3-TPD. The influential factors such as reaction temperature, reaction time, solvent, catalyst amount and substrate concentration were deeply investigated. The optimized fructose conversion rate of 99% with HMF yield of 67% were achieved after 30 min at 140 degrees C in dimethylsulfoxide. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
SubtypeArticle
KeywordBiomass Dehydration 5-hydroxymethylfurfural Layered Transition Metal Oxide Solid Acid
WOS HeadingsScience & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jechem.2016.09.010
WOS Subject ExtendedChemistry ; Energy & Fuels ; Engineering
WOS KeywordCATALYTIC DEHYDRATION ; LEVULINIC ACID ; ION-EXCHANGE ; NIOBIC ACID ; CONVERSION ; NANOSHEETS ; HTAWO6 ; DERIVATIVES ; CHEMICALS ; GLUCOSE
Indexed BySCI
Language英语
Funding OrganizationNational Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010)
WOS SubjectChemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS IDWOS:000401302600019
Citation statistics
Cited Times:6[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/14123
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Zhong, Jiawei,Guo, Yuanyuan,Chen, Jinzhu. Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(1):147-154.
APA Zhong, Jiawei,Guo, Yuanyuan,&Chen, Jinzhu.(2017).Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural.JOURNAL OF ENERGY CHEMISTRY,26(1),147-154.
MLA Zhong, Jiawei,et al."Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural".JOURNAL OF ENERGY CHEMISTRY 26.1(2017):147-154.
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