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Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural
Zhong, Jiawei1,2; Guo, Yuanyuan1; Chen, Jinzhu1
2017
发表期刊JOURNAL OF ENERGY CHEMISTRY
卷号26期号:1页码:147-154
摘要A serial of protonated and layered transition metal oxides, including layered HTaWO6, HNbMoO6 as well as HNbWO6, were synthesized by solid-state reaction and ion-exchange. The layered HTaWO6 has been systematically studied as a solid acid to realize the dehydration of fructose to 5-hydroxymethylfurfural (HMF). The transition metal oxide samples were characterized with ICP-OES, EDS, XRD, XPS, SEM, TGA, FT-IR, N-2 adsorption-desorption and NH3-TPD. The influential factors such as reaction temperature, reaction time, solvent, catalyst amount and substrate concentration were deeply investigated. The optimized fructose conversion rate of 99% with HMF yield of 67% were achieved after 30 min at 140 degrees C in dimethylsulfoxide. (C) 2016 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.
文章类型Article
关键词Biomass Dehydration 5-hydroxymethylfurfural Layered Transition Metal Oxide Solid Acid
WOS标题词Science & Technology ; Physical Sciences ; Technology
资助者National Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010) ; National Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010)
DOI10.1016/j.jechem.2016.09.010
研究领域[WOS]Chemistry ; Energy & Fuels ; Engineering
关键词[WOS]CATALYTIC DEHYDRATION ; LEVULINIC ACID ; ION-EXCHANGE ; NIOBIC ACID ; CONVERSION ; NANOSHEETS ; HTAWO6 ; DERIVATIVES ; CHEMICALS ; GLUCOSE
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010) ; National Natural Science Foundation of China(21472189) ; National Basic Research Program of China (973 Program)(2012CB215304) ; Natural Science Foundation of Guangdong Province, China(2015A030312007) ; Guangdong Key Laboratory of New and Renewable Energy Research and Development(Y607jl1001) ; Science and Technology Planning Project of Guangdong Province, China(2015A010106010)
WOS类目Chemistry, Applied ; Chemistry, Physical ; Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000401302600019
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14123
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
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GB/T 7714
Zhong, Jiawei,Guo, Yuanyuan,Chen, Jinzhu. Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural[J]. JOURNAL OF ENERGY CHEMISTRY,2017,26(1):147-154.
APA Zhong, Jiawei,Guo, Yuanyuan,&Chen, Jinzhu.(2017).Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural.JOURNAL OF ENERGY CHEMISTRY,26(1),147-154.
MLA Zhong, Jiawei,et al."Protonated and layered transition metal oxides as solid acids for dehydration of biomass-based fructose into 5-hydroxymethylfurfural".JOURNAL OF ENERGY CHEMISTRY 26.1(2017):147-154.
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