Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media | |
Chen, Jinzhu1; Huang, Jing1; Chen, Limin2; Ma, Longlong1; Wang, Tiejun1; Zakai, Uzma I.1 | |
2013-06-01 | |
发表期刊 | CHEMCATCHEM |
卷号 | 5期号:6页码:1598-1605 |
摘要 | Using phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. Here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer A-stabilized nanocatalysts and the mineral acid H3PO4. The developed Ru/A-H3PO4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. Mercury poisoning experiments revealed that the insitu generated Ru nanoparticles are true a heterogeneous catalyst for hydrogenation. The catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of Ru>Rh>Pt >> Pd. Our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. The research highlights an efficient catalyst system of transforming phenols into alkanes. |
文章类型 | Article |
关键词 | Biomass Heterogeneous Catalysis Hydrodeoxygenation Ionic Liquids Phenol |
WOS标题词 | Science & Technology ; Physical Sciences |
DOI | 10.1002/cctc.201200582 |
研究领域[WOS] | Chemistry |
关键词[WOS] | FAST PYROLYSIS PROCESSES ; BIO-OILS ; BIOMASS ; CATALYSTS ; ALKANES ; HYDROGENATION ; COMPLEXES ; METAL |
收录类别 | SCI |
语种 | 英语 |
WOS类目 | Chemistry, Physical |
WOS记录号 | WOS:000319680800049 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/10101 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. CHEMCATCHEM,2013,5(6):1598-1605. |
APA | Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.CHEMCATCHEM,5(6),1598-1605. |
MLA | Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".CHEMCATCHEM 5.6(2013):1598-1605. |
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