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Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media
Chen, Jinzhu1; Huang, Jing1; Chen, Limin2; Ma, Longlong1; Wang, Tiejun1; Zakai, Uzma I.1
2013-06-01
Source PublicationCHEMCATCHEM
Volume5Issue:6Pages:1598-1605
AbstractUsing phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. Here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer A-stabilized nanocatalysts and the mineral acid H3PO4. The developed Ru/A-H3PO4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. Mercury poisoning experiments revealed that the insitu generated Ru nanoparticles are true a heterogeneous catalyst for hydrogenation. The catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of Ru>Rh>Pt >> Pd. Our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. The research highlights an efficient catalyst system of transforming phenols into alkanes.
SubtypeArticle
KeywordBiomass Heterogeneous Catalysis Hydrodeoxygenation Ionic Liquids Phenol
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1002/cctc.201200582
WOS Subject ExtendedChemistry
WOS KeywordFAST PYROLYSIS PROCESSES ; BIO-OILS ; BIOMASS ; CATALYSTS ; ALKANES ; HYDROGENATION ; COMPLEXES ; METAL
Indexed BySCI
Language英语
WOS SubjectChemistry, Physical
WOS IDWOS:000319680800049
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/10101
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. CHEMCATCHEM,2013,5(6):1598-1605.
APA Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.CHEMCATCHEM,5(6),1598-1605.
MLA Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".CHEMCATCHEM 5.6(2013):1598-1605.
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