Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media

doi:10.1002/cctc.201200582

GIEC OpenIR > 中国科学院广州能源研究所

	Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media
	Chen, Jinzhu 1; Huang, Jing 1; Chen, Limin 2; Ma, Longlong 1; Wang, Tiejun 1; Zakai, Uzma I.1
	2013-06-01
发表期刊	CHEMCATCHEM
卷号	5 期号:6 页码:1598-1605
摘要	Using phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. Here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer A-stabilized nanocatalysts and the mineral acid H3PO4. The developed Ru/A-H3PO4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. Mercury poisoning experiments revealed that the insitu generated Ru nanoparticles are true a heterogeneous catalyst for hydrogenation. The catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of Ru>Rh>Pt >> Pd. Our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. The research highlights an efficient catalyst system of transforming phenols into alkanes.
文章类型	Article
关键词	Biomass Heterogeneous Catalysis Hydrodeoxygenation Ionic Liquids Phenol
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1002/cctc.201200582
研究领域[WOS]	Chemistry
关键词[WOS]	FAST PYROLYSIS PROCESSES ; BIO-OILS ; BIOMASS ; CATALYSTS ; ALKANES ; HYDROGENATION ; COMPLEXES ; METAL
收录类别	SCI
语种	英语
WOS类目	Chemistry, Physical
WOS记录号	WOS:000319680800049
引用统计	被引频次：26[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/10101
专题	中国科学院广州能源研究所
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. CHEMCATCHEM,2013,5(6):1598-1605.
APA	Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.CHEMCATCHEM,5(6),1598-1605.
MLA	Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".CHEMCATCHEM 5.6(2013):1598-1605.