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Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media
Chen, Jinzhu1; Huang, Jing1; Chen, Limin2; Ma, Longlong1; Wang, Tiejun1; Zakai, Uzma I.1
2013-06-01
发表期刊CHEMCATCHEM
卷号5期号:6页码:1598-1605
摘要Using phenolic bio-oil as feedstock for sustainable production of alkane fuels is of great significance. Here, the hydrodeoxygenation of phenol and its derivatives has been systematically investigated in aqueous media with a dual-functional catalyst system consisting of water-soluble, ionic liquid-like copolymer A-stabilized nanocatalysts and the mineral acid H3PO4. The developed Ru/A-H3PO4 catalyst system achieved a complete phenol conversion with cyclohexane selectivity higher than 99%, making it by far one of the most efficient systems for phenol hydrodeoxygenation. Mercury poisoning experiments revealed that the insitu generated Ru nanoparticles are true a heterogeneous catalyst for hydrogenation. The catalytic activity of metal site for phenol hydrodeoxygenation to cyclohexane decreased with the order of Ru>Rh>Pt >> Pd. Our findings also demonstrated the delicate balance between activity and stability of ionic liquid-like copolymer-stabilized nanocatalysts. The research highlights an efficient catalyst system of transforming phenols into alkanes.
文章类型Article
关键词Biomass Heterogeneous Catalysis Hydrodeoxygenation Ionic Liquids Phenol
WOS标题词Science & Technology ; Physical Sciences
DOI10.1002/cctc.201200582
研究领域[WOS]Chemistry
关键词[WOS]FAST PYROLYSIS PROCESSES ; BIO-OILS ; BIOMASS ; CATALYSTS ; ALKANES ; HYDROGENATION ; COMPLEXES ; METAL
收录类别SCI
语种英语
WOS类目Chemistry, Physical
WOS记录号WOS:000319680800049
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/10101
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy & Nat Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.S China Univ Technol, Coll Environm Sci & Engn, Guangzhou 510006, Guangdong, Peoples R China
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GB/T 7714
Chen, Jinzhu,Huang, Jing,Chen, Limin,et al. Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media[J]. CHEMCATCHEM,2013,5(6):1598-1605.
APA Chen, Jinzhu,Huang, Jing,Chen, Limin,Ma, Longlong,Wang, Tiejun,&Zakai, Uzma I..(2013).Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media.CHEMCATCHEM,5(6),1598-1605.
MLA Chen, Jinzhu,et al."Hydrodeoxygenation of Phenol and Derivatives over an Ionic Liquid-Like Copolymer Stabilized Nanocatalyst in Aqueous Media".CHEMCATCHEM 5.6(2013):1598-1605.
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