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Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose
Li, Yuping1; Liao, Yuhe1,2; Cao, Xiaofeng1,2,3; Wang, Tiejun1; Ma, Longlong1; Long, Jinxing1; Liu, Qiying1; Xua, Ying1
2015-03-01
发表期刊BIOMASS & BIOENERGY
卷号74页码:148-161
摘要In this review, recent advances in the one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose to value-added polyols, including hexitols (sorbitol, mannitol, and isosorbide) and 1,2-alkanediols (ethylene glycol and 1,2-propylene glycol), are summarized. Methods for the generation of H+ in the first step of cellulose hydrolysis to form intermediate sugars, such as the use of soluble acids (mineral acids and heteropoly acids) and H+ produced in situ from functional supports and H-2 dissociation, are classified and analyzed, considering its combination with active metals for the subsequent hydrogenation or hydrogenolysis of sugars to polyols. The interaction of non-noble metals such as nickel, bimetals, and tungsten with support materials in the catalytic conversion of intermediate sugars to hexitols and ethylene glycol is reviewed. The corresponding reaction pathways and mechanisms are discussed, including the conversion process using basic supports and solution conditions. Major challenges and promising routes are also suggested for the future development of the chemocatalytic conversion of cellulose. (C) 2015 Elsevier Ltd. All rights reserved.
文章类型Review
关键词Polyols Cellulose Hydrolytic Hydrogenation/hydrogenolysis Reaction Pathway Catalyst
WOS标题词Science & Technology ; Life Sciences & Biomedicine ; Technology
DOI10.1016/j.biombioe.2014.12.025
研究领域[WOS]Agriculture ; Biotechnology & Applied Microbiology ; Energy & Fuels
关键词[WOS]SUPPORTED CARBIDE CATALYSTS ; SUGAR ALCOHOLS ; SELECTIVE CONVERSION ; MICROCRYSTALLINE CELLULOSE ; PLATFORM CHEMICALS ; TUNGSTEN CARBIDE ; HETEROGENEOUS CATALYSTS ; 1,2-PROPYLENE GLYCOL ; BIMETALLIC CATALYSTS ; PHOSPHIDE CATALYSTS
收录类别SCI
语种英语
WOS类目Agricultural Engineering ; Biotechnology & Applied Microbiology ; Energy & Fuels
WOS记录号WOS:000351789500016
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文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/9103
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
2.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
3.Chinese Acad Sci, Inst Coal Chem, Taiyuan 030001, Peoples R China
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Li, Yuping,Liao, Yuhe,Cao, Xiaofeng,et al. Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose[J]. BIOMASS & BIOENERGY,2015,74:148-161.
APA Li, Yuping.,Liao, Yuhe.,Cao, Xiaofeng.,Wang, Tiejun.,Ma, Longlong.,...&Xua, Ying.(2015).Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose.BIOMASS & BIOENERGY,74,148-161.
MLA Li, Yuping,et al."Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose".BIOMASS & BIOENERGY 74(2015):148-161.
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