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Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen
Du Jianwei; Liang Deqing; Li Dongliang; Li Xinjun
2010-11-17
发表期刊INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
卷号49期号:22页码:11797-11800
产权排序[Du Jianwei; Liang Deqing; Li Dongliang; Li Xinjun(李新军)] CAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
通讯作者Liangdq@ms.giec.ac.cn
摘要In this work, four-phase hydrate equilibrium data for each of the systems cyclopentane (CP) + water + hydrogen, CP + water + nitrogen, and CP + water + oxygen were measured and are reported in the temperature range of 281.3-303.1 K and the pressure range of 2.27-30.40 MPa. Measurements were made using an isochoric method. Experimental data on the equilibrium conditions of the two systems nitrogen + water and hydrogen + water with CP are reported over a previously uninvestigated extended temperature span. The hydrate dissociation data for the CP + water + hydrogen system are compared with some selected experimental data from the literature, and the acceptable agreement demonstrates the reliability of the experimental method used in this work. Finally, the first quadruple phase equilibrium data in the ternary system CP + water + oxygen have been achieved.
文章类型Article
其他摘要In this work, four-phase hydrate equilibrium data for each of the systems cyclopentane (CP) + water + hydrogen, CP + water + nitrogen, and CP + water + oxygen were measured and are reported in the temperature range of 281.3-303.1 K and the pressure range of 2.27-30.40 MPa. Measurements were made using an isochoric method. Experimental data on the equilibrium conditions of the two systems nitrogen + water and hydrogen + water with CP are reported over a previously uninvestigated extended temperature span. The hydrate dissociation data for the CP + water + hydrogen system are compared with some selected experimental data from the literature, and the acceptable agreement demonstrates the reliability of the experimental method used in this work. Finally, the first quadruple phase equilibrium data in the ternary system CP + water + oxygen have been achieved.
关键词Phase-equilibrium Clathrate Hydrate Methyl Cyclohexane Carbon-dioxide Tetrahydropyran
学科领域Engineering
WOS标题词Science & Technology ; Technology
DOI10.1021/ie101339j
研究领域[WOS]Engineering
URL查看原文
关键词[WOS]PHASE-EQUILIBRIUM ; CLATHRATE HYDRATE ; METHYL CYCLOHEXANE ; CARBON-DIOXIDE ; TETRAHYDROPYRAN
收录类别SCI
语种英语
项目资助者National Natural Science Foundation of China [50876107]; National Basic Research Program of China [2009CB219504]; NSFC-Guangdong Union Foundation [U0733003]; CAS [KGCX2-YW-805]
WOS类目Engineering, Chemical
WOS记录号WOS:000283916700077
引用统计
被引频次:15[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/8467
专题中国科学院广州能源研究所
作者单位CAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式
GB/T 7714
Du Jianwei,Liang Deqing,Li Dongliang,et al. Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2010,49(22):11797-11800.
APA Du Jianwei,Liang Deqing,Li Dongliang,&Li Xinjun.(2010).Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,49(22),11797-11800.
MLA Du Jianwei,et al."Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 49.22(2010):11797-11800.
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