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Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen
Du Jianwei; Liang Deqing; Li Dongliang; Li Xinjun
2010-11-17
Source PublicationINDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN0888-5885
Volume49Issue:22Pages:11797-11800
Contribution Rank[Du Jianwei; Liang Deqing; Li Dongliang; Li Xinjun(李新军)] CAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
Corresponding AuthorLiangdq@ms.giec.ac.cn
AbstractIn this work, four-phase hydrate equilibrium data for each of the systems cyclopentane (CP) + water + hydrogen, CP + water + nitrogen, and CP + water + oxygen were measured and are reported in the temperature range of 281.3-303.1 K and the pressure range of 2.27-30.40 MPa. Measurements were made using an isochoric method. Experimental data on the equilibrium conditions of the two systems nitrogen + water and hydrogen + water with CP are reported over a previously uninvestigated extended temperature span. The hydrate dissociation data for the CP + water + hydrogen system are compared with some selected experimental data from the literature, and the acceptable agreement demonstrates the reliability of the experimental method used in this work. Finally, the first quadruple phase equilibrium data in the ternary system CP + water + oxygen have been achieved.
SubtypeArticle
Other AbstractIn this work, four-phase hydrate equilibrium data for each of the systems cyclopentane (CP) + water + hydrogen, CP + water + nitrogen, and CP + water + oxygen were measured and are reported in the temperature range of 281.3-303.1 K and the pressure range of 2.27-30.40 MPa. Measurements were made using an isochoric method. Experimental data on the equilibrium conditions of the two systems nitrogen + water and hydrogen + water with CP are reported over a previously uninvestigated extended temperature span. The hydrate dissociation data for the CP + water + hydrogen system are compared with some selected experimental data from the literature, and the acceptable agreement demonstrates the reliability of the experimental method used in this work. Finally, the first quadruple phase equilibrium data in the ternary system CP + water + oxygen have been achieved.
KeywordPhase-equilibrium Clathrate Hydrate Methyl Cyclohexane Carbon-dioxide Tetrahydropyran
Subject AreaEngineering
WOS HeadingsScience & Technology ; Technology
DOI10.1021/ie101339j
WOS Subject ExtendedEngineering
URL查看原文
WOS KeywordPHASE-EQUILIBRIUM ; CLATHRATE HYDRATE ; METHYL CYCLOHEXANE ; CARBON-DIOXIDE ; TETRAHYDROPYRAN
Indexed BySCI
Language英语
Funding OrganizationNational Natural Science Foundation of China [50876107]; National Basic Research Program of China [2009CB219504]; NSFC-Guangdong Union Foundation [U0733003]; CAS [KGCX2-YW-805]
WOS SubjectEngineering, Chemical
WOS IDWOS:000283916700077
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/8467
Collection中国科学院广州能源研究所
AffiliationCAS, Key Lab Renewable Energy & Gas Hydrate, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
Recommended Citation
GB/T 7714
Du Jianwei,Liang Deqing,Li Dongliang,et al. Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen[J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,2010,49(22):11797-11800.
APA Du Jianwei,Liang Deqing,Li Dongliang,&Li Xinjun.(2010).Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen.INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH,49(22),11797-11800.
MLA Du Jianwei,et al."Experimental Determination of the Equilibrium Conditions of Binary Gas Hydrates of Cyclopentane plus Oxygen, Cyclopentane plus Nitrogen, and Cyclopentane plus Hydrogen".INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH 49.22(2010):11797-11800.
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