Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst | |
Chen, Lungang1; Liu, Yong2,3,4; Gu, Canshuo1; Feng, Gang5; Zhang, Xinghua1 ; Liu, Jianguo1; Zhang, Qi1; Wang, Chenguang2; Ma, Longlong1
| |
| 2021-11-22 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
 |
| ISSN | 2168-0485 |
| Volume | 9Issue:46Pages:15603-15611 |
| Corresponding Author | Wang, Chenguang(wangcg@ms.giec.ac.cn) |
| Abstract | Selective production of 2-butanol from levulinic acid (LA) hydro-genolysis over a non-precious catalyst is long desirable. However, the process requires the precious metal Ru, and the yield of 2-butanol was less than 65%. Herein, we prepared Ni-based bimetallic catalysts, among which the NiMn catalyst exhibited the highest efficiency and reached an 84.5% yield of 2-butanol at 100% LA conversion under optimal conditions. The electronic states and surface properties were characterized by various techniques such as X-ray diffraction, X-ray photoelectron spectroscopy, temperature-programmed desorption, temperatureprogrammed reduction, and scanning electron microscopy/transmission electron microscopy. The high efficiency of the NiMn catalyst was due to the synergy between Ni-0 and Mn2+ species, and the modified surface showed a high basicity and a high affinity to adsorb LA and LA-derived molecules with C = O or COOH. The high affinity of the NiMn catalyst was further confirmed by density functional theory calculations. |
| Keyword | biomass levulinic acid 2-butanol hydrogenolysis DFT |
| DOI | 10.1021/acssuschemeng.1c05771 |
| WOS Keyword | GAMMA-VALEROLACTONE ; CONVERSION ; CELLULOSE ; BIOMASS ; 2-METHYLTETRAHYDROFURAN ; HYDROGENATION ; BASICITY ; CHEMICALS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Key R&D Program of China[2019YFD1100601] ; National Natural Science Foundation of China[21878290] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Key R&D Program of China ; National Natural Science Foundation of China |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000753951700025 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/35846 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Wang, Chenguang |
| Affiliation | 1.Southeast Univ, Sch Energy & Environm, Key Lab Energy Thermal Convers & Control, Minist Educ, Nanjing 210096, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Peoples R China 3.Nanchang Univ, Sch Resources Environm & Chem Engn, Nanchang 330031, Jiangxi, Peoples R China 4.Nanchang Univ, Key Lab Poyang Lake Environm & Resource Utilizat, Minist Educ, Nanchang 330031, Jiangxi, Peoples R China 5.Nanchang Univ, Coll Chem, Inst Appl Chem, Key Lab Jiangxi Prov Environm & Energy Catalysis, Nanchang 330031, Jiangxi, Peoples R China |
| Recommended Citation GB/T 7714 | Chen, Lungang,Liu, Yong,Gu, Canshuo,et al. Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2021,9(46):15603-15611. |
| APA | Chen, Lungang.,Liu, Yong.,Gu, Canshuo.,Feng, Gang.,Zhang, Xinghua.,...&Ma, Longlong.(2021).Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,9(46),15603-15611. |
| MLA | Chen, Lungang,et al."Selective Production of 2-Butanol from Hydrogenolysis of Levulinic Acid Catalyzed by the Non-precious NiMn Bimetallic Catalyst".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 9.46(2021):15603-15611. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment