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Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT
Li, Xiao-Sen; Wu, Hui-Jie; Li, Yi-Gui; Feng, Zi-Ping; Tang, Liang-Guang; Fan, Shuan-Shi
2007-03-01
发表期刊JOURNAL OF CHEMICAL THERMODYNAMICS
ISSN0021-9614
卷号39期号:3页码:417-425
通讯作者lixs@ms.giec.ac.cn
摘要A new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. The statistical associating fluid theory (SAFT) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der Waals and Platteeuw for the hydrate phase. The predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data. (c) 2006 Elsevier Ltd. All rights reserved.
文章类型Article
其他摘要A new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. The statistical associating fluid theory (SAFT) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der Waals and Platteeuw for the hydrate phase. The predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data.
关键词Hydrate Saft Equation Of State Phase Equilibria Gas Mixture
WOS标题词Science & Technology ; Physical Sciences
DOI10.1016/j.jct.2006.07.028
研究领域[WOS]Thermodynamics ; Chemistry
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关键词[WOS]EQUATION-OF-STATE ; THERMODYNAMIC PERTURBATION-THEORY ; VAPOR-LIQUID-EQUILIBRIUM ; TREBBLE-BISHNOI EQUATION ; ASSOCIATING FLUIDS ; PHASE-EQUILIBRIA ; PREDICTION ; METHANOL ; SYSTEMS ; WATER
收录类别SCI
语种英语
WOS类目Thermodynamics ; Chemistry, Physical
WOS记录号WOS:000244649100007
引用统计
被引频次:42[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/3488
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China
推荐引用方式
GB/T 7714
Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,et al. Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2007,39(3):417-425.
APA Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,Feng, Zi-Ping,Tang, Liang-Guang,&Fan, Shuan-Shi.(2007).Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT.JOURNAL OF CHEMICAL THERMODYNAMICS,39(3),417-425.
MLA Li, Xiao-Sen,et al."Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT".JOURNAL OF CHEMICAL THERMODYNAMICS 39.3(2007):417-425.
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