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Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT
Li, Xiao-Sen; Wu, Hui-Jie; Li, Yi-Gui; Feng, Zi-Ping; Tang, Liang-Guang; Fan, Shuan-Shi
2007-03-01
Source PublicationJOURNAL OF CHEMICAL THERMODYNAMICS
ISSN0021-9614
Volume39Issue:3Pages:417-425
Corresponding Authorlixs@ms.giec.ac.cn
AbstractA new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. The statistical associating fluid theory (SAFT) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der Waals and Platteeuw for the hydrate phase. The predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data. (c) 2006 Elsevier Ltd. All rights reserved.
SubtypeArticle
Other AbstractA new method, a molecular thermodynamic model based on statistical mechanics, is employed to predict the hydrate dissociation conditions for binary gas mixtures with carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons in the presence of aqueous solutions. The statistical associating fluid theory (SAFT) equation of state is employed to characterize the vapor and liquid phases and the statistical model of van der Waals and Platteeuw for the hydrate phase. The predictions of the proposed model were found to be in satisfactory to excellent agreement with the experimental data.
KeywordHydrate Saft Equation Of State Phase Equilibria Gas Mixture
WOS HeadingsScience & Technology ; Physical Sciences
DOI10.1016/j.jct.2006.07.028
WOS Subject ExtendedThermodynamics ; Chemistry
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WOS KeywordEQUATION-OF-STATE ; THERMODYNAMIC PERTURBATION-THEORY ; VAPOR-LIQUID-EQUILIBRIUM ; TREBBLE-BISHNOI EQUATION ; ASSOCIATING FLUIDS ; PHASE-EQUILIBRIA ; PREDICTION ; METHANOL ; SYSTEMS ; WATER
Indexed BySCI
Language英语
WOS SubjectThermodynamics ; Chemistry, Physical
WOS IDWOS:000244649100007
Citation statistics
Cited Times:42[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/3488
Collection中国科学院广州能源研究所
Affiliation1.Chinese Acad Sci, Inst Energy Convers, Guangzhou 510640, Peoples R China
2.Tsinghua Univ, Dept Chem Engn, State Key Lab Chem Engn, Beijing 100084, Peoples R China
Recommended Citation
GB/T 7714
Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,et al. Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT[J]. JOURNAL OF CHEMICAL THERMODYNAMICS,2007,39(3):417-425.
APA Li, Xiao-Sen,Wu, Hui-Jie,Li, Yi-Gui,Feng, Zi-Ping,Tang, Liang-Guang,&Fan, Shuan-Shi.(2007).Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT.JOURNAL OF CHEMICAL THERMODYNAMICS,39(3),417-425.
MLA Li, Xiao-Sen,et al."Hydrate dissociation conditions for gas mixtures containing carbon dioxide, hydrogen, hydrogen sulfide, nitrogen, and hydrocarbons using SAFT".JOURNAL OF CHEMICAL THERMODYNAMICS 39.3(2007):417-425.
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