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The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol
Liu, N; Yuan, ZS; Wang, CW; Wang, SD; Zhang, CX; Wang, SJ
2008
Source PublicationFUEL PROCESSING TECHNOLOGY
ISSN0378-3820
Volume89Issue:6Pages:574-581
Corresponding Authorwangsd@dicp.ac.cn
Other AbstractAutothermal reforming of methanol for hydrogen production was investigated over ZnO-ZnCr2O4 supported on a series of metal oxides (Al2O3, CeO2, ZrO2 and CeO2-ZrO2)CeO2-ZrO2 mixed oxides with Ce /Zr molar ratio of 4/1 was found to be the optimal support which showed significant effect on the catalytic activity and selectivity. The ZnO-ZnCr2O4/CeO2-ZrO2 and ZnO-ZnCr2O4 catalysts were characterized by XRD, TEM, H-2-TPR and XPS. The results show that CeO2-ZrO2 mixed oxides have significant effect on the catalytic performance and the supported catalyst shows more uniform temperature distribution in the catalyst bed which was mainly due to its reasonable redox properties.
KeywordHydrogen Production Methanol Autothermal Reforming Zno Ceo2-zro2 Alcohol Synthesis Catalysts Fuel-cell Applications Hydrogen-production Surface Characterization Cuo/ceo2 Catalysts Redox Behavior Zn/cr Spinel Mixed Oxides Pd/zno Performance
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Indexed BySCI
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/3424
Collection中国科学院广州能源研究所
Recommended Citation
GB/T 7714
Liu, N,Yuan, ZS,Wang, CW,et al. The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol[J]. FUEL PROCESSING TECHNOLOGY,2008,89(6):574-581.
APA Liu, N,Yuan, ZS,Wang, CW,Wang, SD,Zhang, CX,&Wang, SJ.(2008).The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol.FUEL PROCESSING TECHNOLOGY,89(6),574-581.
MLA Liu, N,et al."The role of CeO2-ZrO2 as support in the ZnO-ZnCr2O4 catalysts for autothermal reforming of methanol".FUEL PROCESSING TECHNOLOGY 89.6(2008):574-581.
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