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Direct production of biodiesel via simultaneous esterification and transesterification of renewable oils using calcined blast furnace dust
Wang, Yi-Tong1; Cong, Wen-Jie2; Zeng, Ya-Nan1; Zhang, Yu-Qing4; Liang, Jing-Long1; Li, Jun-Guo1; Jiang, Li-Qun3; Fang, Zhen2
2021-09-01
发表期刊RENEWABLE ENERGY
ISSN0960-1481
卷号175页码:1001-1011
通讯作者Zeng, Ya-Nan(zengyanan@ncst.edu.cn) ; Jiang, Li-Qun(lqjiang@ms.giec.ac.cn) ; Fang, Zhen(zhenfang@njau.edu.cn)
摘要Direct production of biodiesel by both esterification and transesterification of renewable oils with acid value (AV) of 9.6-28.9 mg KOH/g using calcined blast furnace dust is studied. Blast furnace dust calcined at 600-700 degrees C obviously promotes efficient biodiesel production because of the crystal form transformation from lead sulfate particles in dust into active lead oxide, lead sulfide, and lead particles. It is found for the first time that lead oxide, lead sulfide and lead particles can resist saponification from fatty acids to catalyze raw renewable oils to biodiesel with catalytic activity order as follows: lead oxide > lead > lead sulfide > lead sulfate. Biodiesel production process is optimized according to an orthogonal design with biodiesel yield of 92 wt% obtained at AV of 9.6 mg KOH/g (82 wt% after 5 cycles). Biodiesel yield of 84 wt% is achieved at AV of 28.9 mg KOH/g with acidity of 0.18 mmol/g. Calcined blast furnace dust presents potential applications in the production of biodiesel from renewable oils with high AVs. (C) 2021 Elsevier Ltd. All rights reserved.
关键词Blast furnace dust Solid industrial waste Waste recycling Biodiesel Renewable Jatropha oils Biofuels
DOI10.1016/j.renene.2021.05.013
关键词[WOS]ONE-STEP PRODUCTION ; HIGH ACID VALUE ; SOYBEAN OIL ; JATROPHA-CURCAS ; CORE-SHELL ; CATALYST ; REDUCTION ; CARBON ; FUEL ; NANOPARTICLES
收录类别SCI
语种英语
资助项目National Natural Science Foundation of China[52004095] ; National Natural Science Foundation of China[51704119] ; National Natural Science Foundation of China[21878161] ; Natural Science Foundation of Hebei Province[E2017209243] ; Department of Education of Hebei Province[BJ2019038] ; Guangdong Basic and Applied Basic Research Foundation[2021A1515012063] ; Youth Innovation Promotion Association CAS[2021350]
WOS研究方向Science & Technology - Other Topics ; Energy & Fuels
项目资助者National Natural Science Foundation of China ; Natural Science Foundation of Hebei Province ; Department of Education of Hebei Province ; Guangdong Basic and Applied Basic Research Foundation ; Youth Innovation Promotion Association CAS
WOS类目Green & Sustainable Science & Technology ; Energy & Fuels
WOS记录号WOS:000658657000003
出版者PERGAMON-ELSEVIER SCIENCE LTD
引用统计
被引频次:12[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/33371
专题中国科学院广州能源研究所
通讯作者Zeng, Ya-Nan; Jiang, Li-Qun; Fang, Zhen
作者单位1.North China Univ Sci & Technol, Coll Met & Energy, 21 Bohai St, Tangshan 063210, Peoples R China
2.Nanjing Agr Univ, Coll Engn, Biomass Grp, 40 Dianjiangtai Rd, Nanjing 210031, Jiangsu, Peoples R China
3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Peoples R China
4.KTH Royal Inst Technol, Sch Ind Engn & Management, S-10044 Stockholm, Sweden
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GB/T 7714
Wang, Yi-Tong,Cong, Wen-Jie,Zeng, Ya-Nan,et al. Direct production of biodiesel via simultaneous esterification and transesterification of renewable oils using calcined blast furnace dust[J]. RENEWABLE ENERGY,2021,175:1001-1011.
APA Wang, Yi-Tong.,Cong, Wen-Jie.,Zeng, Ya-Nan.,Zhang, Yu-Qing.,Liang, Jing-Long.,...&Fang, Zhen.(2021).Direct production of biodiesel via simultaneous esterification and transesterification of renewable oils using calcined blast furnace dust.RENEWABLE ENERGY,175,1001-1011.
MLA Wang, Yi-Tong,et al."Direct production of biodiesel via simultaneous esterification and transesterification of renewable oils using calcined blast furnace dust".RENEWABLE ENERGY 175(2021):1001-1011.
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