Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom | |
| Sun, Ruiyan1; Liao, Yuhe1,2; Bai, Shao-Tao1; Zheng, Mingyuan3; Zhou, Cheng1; Zhang, Tao3; Sels, Bert F.1 | |
| 2021-03-01 | |
| Source Publication | ENERGY & ENVIRONMENTAL SCIENCE
 |
| ISSN | 1754-5692 |
| Volume | 14Issue:3Pages:1247-1285 |
| Corresponding Author | Zhang, Tao(taozhang@dicp.ac.cn) ; Sels, Bert F.(bert.sels@kuleuven.be) |
| Abstract | Propelled by the vision of carbon-neutral energy systems, heterogeneous hydrogenation of CO2 to formic acid/formate, a liquid hydrogen carrier, has been intensively studied as a promising approach to realize renewable and decarbonized energy supply. In the present review, the state-of-the-art of heterogeneous catalysts for this process is comprehensively summarized. First, a brief description of the challenges associated with thermodynamics is provided. Major advancements on constructing efficient heterogeneous catalysts then constitute the main body of this review, mainly involving nanostructured and single atom catalysts based on noble metals. Special attention is paid to the relevant structure-activity correlations and mechanistic insights, which provide strong bases for rational catalyst design. Key factors related to catalytic activity are highlighted including metal dispersion, electron density, basic functionalities, and concerted catalysis of metal and basic sites. A summary and outlook is presented in the end. We believe that this review will inspire more novel research from the catalysis community to advance the design of innovative catalytic materials towards the ultimate sustainable energy sector with a closed carbon loop. |
| DOI | 10.1039/d0ee03575k |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | KU Leuven through the C2 research program ; National Key Projects for Fundamental Research and Development of China[2016YFA0202801] ; National Natural Science Foundation of China[21690081] ; Biorefineries Featuring Carbon Dioxide Capturing and Utilization Project |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering ; Environmental Sciences & Ecology |
| Funding Organization | KU Leuven through the C2 research program ; National Key Projects for Fundamental Research and Development of China ; National Natural Science Foundation of China ; Biorefineries Featuring Carbon Dioxide Capturing and Utilization Project |
| WOS Subject | Chemistry, Multidisciplinary ; Energy & Fuels ; Engineering, Chemical ; Environmental Sciences |
| WOS ID | WOS:000639555200006 |
| Publisher | ROYAL SOC CHEMISTRY |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/32975 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Tao; Sels, Bert F. |
| Affiliation | 1.Katholieke Univ Leuven, Fac Biosci, Ctr Sustainable Catalysis & Engn, Celestijnenlaan 200F, B-3001 Heverlee, Belgium 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Dalian Inst Chem Phys, State Key Lab Catalysis, Dalian 116023, Peoples R China |
| Recommended Citation GB/T 7714 | Sun, Ruiyan,Liao, Yuhe,Bai, Shao-Tao,et al. Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom[J]. ENERGY & ENVIRONMENTAL SCIENCE,2021,14(3):1247-1285. |
| APA | Sun, Ruiyan.,Liao, Yuhe.,Bai, Shao-Tao.,Zheng, Mingyuan.,Zhou, Cheng.,...&Sels, Bert F..(2021).Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom.ENERGY & ENVIRONMENTAL SCIENCE,14(3),1247-1285. |
| MLA | Sun, Ruiyan,et al."Heterogeneous catalysts for CO2 hydrogenation to formic acid/formate: from nanoscale to single atom".ENERGY & ENVIRONMENTAL SCIENCE 14.3(2021):1247-1285. |
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