Superorganophilic MAF-6/PP Composite Separator Boosts Lithium Metal Anode Performance

doi:10.1016/j.ensm.2021.02.021

GIEC OpenIR

	Superorganophilic MAF-6/PP Composite Separator Boosts Lithium Metal Anode Performance
	Wu, Wen-Li 1; Xu, Yan-Tong 2,3; Ke, Xi 1; Chen, Yuan-Mao 1; Cheng, Yi-Feng 1; Lin, Gui-De 1; Fan, Mou-Ping 1; Liu, Li-Ying 1; Shi, Zhi-Cong 1
	2021-05-01
Source Publication	ENERGY STORAGE MATERIALS
ISSN	2405-8297
Volume	37 Pages:387-395
Corresponding Author	Ke, Xi(kexi@gdut.edu.cn)
Abstract	Practical application of lithium metal anodes in high-energy rechargeable batteries is impeded by the issue of Li dendrite growth. Herein, an exceptional hydrophobic MAF-6 material is utilized to modify polypropylene (PP) separator to yield a superorganophilic MAF-6/PP composite separator. Owing to a combination of super-organophilicity with three-dimensional ordered porosity, the MAF-6/PP achieves a Li ion transference number of 0.78. Homogeneous and dense Li plating behaviors are present in cells with MAF-6/PP which can afford uniform Li ion flux. The MAF-6/PP enables Li vertical bar Cu cells to run steadily for over 350 cycles at 0.5 mA cm(-2) -1 mAh cm(-2) with an average coulombic efficiency (CE) of 98.8%, symmetric Li vertical bar Li cells to work stably for 2200 h without short-circuit at 0.5 mA cm(-2)-1 mAh cm(-2), and Li vertical bar LiFePO4 cells to retain a reversible capacity of 102.4 mAh g(-1) after 1500 cycles at 1C with a capacity retention of 73.2% and a CE of 99.9%.
Keyword	Lithium metal anodes Metal-organic frameworks Separators Superorganophilicity
DOI	10.1016/j.ensm.2021.02.021
Indexed By	SCI
Language	英语
Funding Project	National Key R&D Program of China[2018YFB0104200]
WOS Research Area	Chemistry ; Science & Technology - Other Topics ; Materials Science
Funding Organization	National Key R&D Program of China
WOS Subject	Chemistry, Physical ; Nanoscience & Nanotechnology ; Materials Science, Multidisciplinary
WOS ID	WOS:000632780200002
Publisher	ELSEVIER
Citation statistics	Cited Times:20[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/32892
Collection	中国科学院广州能源研究所
Corresponding Author	Ke, Xi
Affiliation	1.Guangdong Univ Technol, Sch Mat & Energy, Dept New Energy Mat & Devices, Guangzhou 510006, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Peoples R China 3.Sun Yat Sen Univ, Sch Chem, MOE Key Lab Bioinorgan & Synthet Chem, Guangzhou 510275, Peoples R China
Recommended Citation GB/T 7714	Wu, Wen-Li,Xu, Yan-Tong,Ke, Xi,et al. Superorganophilic MAF-6/PP Composite Separator Boosts Lithium Metal Anode Performance[J]. ENERGY STORAGE MATERIALS,2021,37:387-395.
APA	Wu, Wen-Li.,Xu, Yan-Tong.,Ke, Xi.,Chen, Yuan-Mao.,Cheng, Yi-Feng.,...&Shi, Zhi-Cong.(2021).Superorganophilic MAF-6/PP Composite Separator Boosts Lithium Metal Anode Performance.ENERGY STORAGE MATERIALS,37,387-395.
MLA	Wu, Wen-Li,et al."Superorganophilic MAF-6/PP Composite Separator Boosts Lithium Metal Anode Performance".ENERGY STORAGE MATERIALS 37(2021):387-395.

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