Influence of Particle Size on the Heat and Mass Transfer Characteristics of Methane Hydrate Formation and Decomposition in Porous Media

doi:10.1021/acs.energyfuels.0c03812

GIEC OpenIR

	Influence of Particle Size on the Heat and Mass Transfer Characteristics of Methane Hydrate Formation and Decomposition in Porous Media
	Li, Xiao-Yan 1,2,3,4; Li, Xiao-Sen1,2,3 ; Wang, Yi 1,2,3; Li, Gang1,2,3 ; Zhang, Yu1,2,3 ; Hu, Heng-Qi 1,2,3,5; Wan, Kun 1,2,3,4; Zeng, Hao-Peng 1,2,3,4
	2021-02-04
发表期刊	ENERGY & FUELS
ISSN	0887-0624
卷号	35 期号:3 页码:2153-2164
通讯作者	Li, Xiao-Sen(lixs@ms.giec.ac.cn) ; Wang, Yi(wangyi@ms.giec.ac.cn)
摘要	In nature, permafrost regions and deep ocean sediments contain a large amount of gas hydrate. As a basic property of the sediments, the particle size of the porous media is a critical factor affecting hydrate production. In this study, methane hydrate formed and dissociated in the sediments with different particle sizes, including the particle sizes of 14-20 mesh, 35-60 mesh, 80120 mesh, and 400-500 mesh. The experimental results showed that two stages were included during the hydrate formation process. In the first stage, the hydrate was mainly formed in the upper of the sediments, which hindered the further contact of gas/water and resulted in the decrease of the hydrate formation rate in the second stage. As the particle size of the porous media decreased, the induction time for the hydrate nucleation decreased and the hydrate formation rate increased. In the porous media with 400-500 mesh, the hydrate started forming while the gas was injected into the hydrate simulator. It was found that the hydrate formation rate in the sediments was limited by the mass transport rate of gas and water. In the constant pressure stage (CPS) of the hydrate dissociation, the maximum value of the hydrate dissociation rate was obtained in the porous media with 35-60 mesh. It was found for the first time that the change characteristics of the average hydrate dissociation rate with the medium particle size of the porous media were similar to those of the effective thermal conductivity with the medium particle size of the porous media. This demonstrated that the heat transfer rate of the sediments determined the hydrate dissociation rate, and the influences of the capillary force and the hydrate distribution on the hydrate dissociation were minor. The experimental results also suggested that the coarsedominated sediments are more advantageous for gas hydrate production.
DOI	10.1021/acs.energyfuels.0c03812
关键词[WOS]	GAS-PRODUCTION ; DISSOCIATION ; RECOVERY ; WATER ; DEPRESSURIZATION ; STIMULATION ; BEHAVIORS ; WELLBORE ; BED
收录类别	SCI
语种	英语
资助项目	Key Program of National Natural Science Foundation of China[51736009] ; National Natural Science Foundation of China[51676190] ; National Natural Science Foundation of China[51806251] ; Guangdong Special Support Program-Local innovation and entrepreneurship team project[2019BT02L278] ; Special Project for Marine Economy Development of Guangdong Province[GDME-2018D002] ; Science and Technology Apparatus Development Program of the Chinese Academy of Sciences[YZ201619] ; Frontier Sciences Key Research Program of the Chinese Academy of Sciences[QYZDJ-SSW-JSC033] ; Youth Science and Technology Innovation Talent of Guangdong[2016TQ03Z862] ; Youth Innovation Promotion Association CAS[2018382]
WOS研究方向	Energy & Fuels ; Engineering
项目资助者	Key Program of National Natural Science Foundation of China ; National Natural Science Foundation of China ; Guangdong Special Support Program-Local innovation and entrepreneurship team project ; Special Project for Marine Economy Development of Guangdong Province ; Science and Technology Apparatus Development Program of the Chinese Academy of Sciences ; Frontier Sciences Key Research Program of the Chinese Academy of Sciences ; Youth Science and Technology Innovation Talent of Guangdong ; Youth Innovation Promotion Association CAS
WOS类目	Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000627568300022
出版者	AMER CHEMICAL SOC
引用统计	被引频次：30[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/32842
专题	中国科学院广州能源研究所
通讯作者	Li, Xiao-Sen; Wang, Yi
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 3.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Peoples R China 4.Univ Chinese Acad Sci, Beijing 100049, Peoples R China 5.Univ Sci & Technol China, Hefei 230000, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Li, Xiao-Yan,Li, Xiao-Sen,Wang, Yi,et al. Influence of Particle Size on the Heat and Mass Transfer Characteristics of Methane Hydrate Formation and Decomposition in Porous Media[J]. ENERGY & FUELS,2021,35(3):2153-2164.
APA	Li, Xiao-Yan.,Li, Xiao-Sen.,Wang, Yi.,Li, Gang.,Zhang, Yu.,...&Zeng, Hao-Peng.(2021).Influence of Particle Size on the Heat and Mass Transfer Characteristics of Methane Hydrate Formation and Decomposition in Porous Media.ENERGY & FUELS,35(3),2153-2164.
MLA	Li, Xiao-Yan,et al."Influence of Particle Size on the Heat and Mass Transfer Characteristics of Methane Hydrate Formation and Decomposition in Porous Media".ENERGY & FUELS 35.3(2021):2153-2164.