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Enhanced Electrochemical Performance by In Situ Phase Transition from SnS2 Nanoparticles to SnS Nanorods in N-Doped Hierarchical Porous Carbon as Anodes for Lithium-Ion Batteries
Hu, Qianqian1,2,3; Wang, Biao1,3,4; Hu, Chunjiao2; Hu, Yunjian2; Lu, Jiqun1,3; Dong, Haiyong2; Wu, Chunyu2; Chang, Shiyong2; Zhang, Lingzhi1,3
2020-11-23
Source PublicationACS APPLIED ENERGY MATERIALS
ISSN2574-0962
Volume3Issue:11Pages:11318-11325
Corresponding AuthorChang, Shiyong() ; Zhang, Lingzhi(lzzhang@ms.giec.ac.cn)
AbstractTin sulfides have attracted great attention as promising anode materials for lithium-ion batteries due to their high theoretical specific capacity. However, the rapid capacity decay, resulting from the structural instability of tin-sulfide-based anodes over cycling, impedes its practical applications. Herein, the simple and controllable synthesis of one-dimensional (1D) SnS nanorods decorated in N-doped hierarchical porous carbon (N-HPC/SnS) through in situ phase transformation from N-HPC/SnS2 under thermal annealing is carried out. This structural design leads to fast ion/electron transport and enough space for volume variations. The resultant electrochemical test verifies the advantages of the as-developed materials, which exhibits great cycling stability with a high specific capacity of 638.74 mAh/g over 800 cycles at 0.5 A/g.
KeywordSnS nanorod N-doped hierarchical porous carbon structural phase transformation cycling stability lithium-ion battery
DOI10.1021/acsaem.0c02257
Indexed BySCI
Language英语
Funding ProjectK.C. Wong Education Foundation ; National Natural Science Foundation of China[21573239] ; Guangzhou Automobile Group Co., Ltd., China
WOS Research AreaChemistry ; Energy & Fuels ; Materials Science
Funding OrganizationK.C. Wong Education Foundation ; National Natural Science Foundation of China ; Guangzhou Automobile Group Co., Ltd., China
WOS SubjectChemistry, Physical ; Energy & Fuels ; Materials Science, Multidisciplinary
WOS IDWOS:000595488500103
PublisherAMER CHEMICAL SOC
Citation statistics
Cited Times:15[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/32511
Collection中国科学院广州能源研究所
Corresponding AuthorChang, Shiyong; Zhang, Lingzhi
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China
2.GAC Automot Res & Dev Ctr, Guangzhou 511434, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Hu, Qianqian,Wang, Biao,Hu, Chunjiao,et al. Enhanced Electrochemical Performance by In Situ Phase Transition from SnS2 Nanoparticles to SnS Nanorods in N-Doped Hierarchical Porous Carbon as Anodes for Lithium-Ion Batteries[J]. ACS APPLIED ENERGY MATERIALS,2020,3(11):11318-11325.
APA Hu, Qianqian.,Wang, Biao.,Hu, Chunjiao.,Hu, Yunjian.,Lu, Jiqun.,...&Zhang, Lingzhi.(2020).Enhanced Electrochemical Performance by In Situ Phase Transition from SnS2 Nanoparticles to SnS Nanorods in N-Doped Hierarchical Porous Carbon as Anodes for Lithium-Ion Batteries.ACS APPLIED ENERGY MATERIALS,3(11),11318-11325.
MLA Hu, Qianqian,et al."Enhanced Electrochemical Performance by In Situ Phase Transition from SnS2 Nanoparticles to SnS Nanorods in N-Doped Hierarchical Porous Carbon as Anodes for Lithium-Ion Batteries".ACS APPLIED ENERGY MATERIALS 3.11(2020):11318-11325.
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