Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel

doi:10.1021/acssuschemeng.0c01457

GIEC OpenIR

	Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel
	Chen, Qiang 1,3; Cai, Chiliu1 ; Zhang, Xinghua1,2 ; Zhang, Qi1 ; Chen, Lungang 1; Li, Yuping1 ; Wang, Chenguang 1; Ma, Longlong1
	2020-06-29
发表期刊	ACS SUSTAINABLE CHEMISTRY & ENGINEERING
ISSN	2168-0485
卷号	8 期号:25 页码:9335-9345
通讯作者	Zhang, Xinghua(zhangxh@ms.giec.ac.cn)
摘要	To obtain naphthenic fuel from lignin-derived phenolic compounds, an inexpensive amorphous catalyst FeNi-ZrO2 catalyst has been prepared by a cocrystallization method using the pristine Ni(NO3)(2), Fe(NO3)(3) and Zr(NO3)(4) as precursors. The catalyst was characterized systematically and tested by hydrodeoxygenation (HDO) using guaiacol as reactant. The results show that the amorphous FeNi-ZrO2 possesses an excellent texture structure and high catalytic activity. Guaiacol was completely converted with a yield of 98.5% hydrocarbons over the FeNi-ZrO2 catalyst with a content of 24 wt % Fe and 6 wt % Ni. It is found that iron is conducive to weaken the bond of C-O due to its oxygen affinity, promoting an improvement of the catalytic activity. Furthermore, lignin depolymerization products (LDP) were also converted to cycloalkanes with a yield of 48.39 wt %, suggesting that the amorphous FeNi-ZrO2 catalyst has a universal catalytic capacity in the HDO reaction of phenolic compounds.
关键词	Amorphous FeNi-ZrO2 Guaiacol Lignin depolymerization product (LDP) Hydrodeoxygenation (HDO) Cycloalkanes
DOI	10.1021/acssuschemeng.0c01457
关键词[WOS]	GAS-PHASE HYDRODEOXYGENATION ; MODEL COMPOUNDS ; CATALYTIC HYDRODEOXYGENATION ; CARBON NANOTUBES ; PYROLYSIS OIL ; FE CATALYSTS ; HYDROGENATION ; GUAIACOL ; DEPOLYMERIZATION ; DECOMPOSITION
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51876210] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program[2019TQ05L238] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Chemistry ; Science & Technology - Other Topics ; Engineering
项目资助者	National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical
WOS记录号	WOS:000545975600012
出版者	AMER CHEMICAL SOC
引用统计	被引频次：56[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/27427
专题	中国科学院广州能源研究所
通讯作者	Zhang, Xinghua
作者单位	1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Chen, Qiang,Cai, Chiliu,Zhang, Xinghua,et al. Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(25):9335-9345.
APA	Chen, Qiang.,Cai, Chiliu.,Zhang, Xinghua.,Zhang, Qi.,Chen, Lungang.,...&Ma, Longlong.(2020).Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(25),9335-9345.
MLA	Chen, Qiang,et al."Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.25(2020):9335-9345.