Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel | |
Chen, Qiang1,3; Cai, Chiliu1 ; Zhang, Xinghua1,2; Zhang, Qi1; Chen, Lungang1; Li, Yuping1; Wang, Chenguang1; Ma, Longlong1
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| 2020-06-29 | |
| Source Publication | ACS SUSTAINABLE CHEMISTRY & ENGINEERING
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| ISSN | 2168-0485 |
| Volume | 8Issue:25Pages:9335-9345 |
| Corresponding Author | Zhang, Xinghua(zhangxh@ms.giec.ac.cn) |
| Abstract | To obtain naphthenic fuel from lignin-derived phenolic compounds, an inexpensive amorphous catalyst FeNi-ZrO2 catalyst has been prepared by a cocrystallization method using the pristine Ni(NO3)(2), Fe(NO3)(3) and Zr(NO3)(4) as precursors. The catalyst was characterized systematically and tested by hydrodeoxygenation (HDO) using guaiacol as reactant. The results show that the amorphous FeNi-ZrO2 possesses an excellent texture structure and high catalytic activity. Guaiacol was completely converted with a yield of 98.5% hydrocarbons over the FeNi-ZrO2 catalyst with a content of 24 wt % Fe and 6 wt % Ni. It is found that iron is conducive to weaken the bond of C-O due to its oxygen affinity, promoting an improvement of the catalytic activity. Furthermore, lignin depolymerization products (LDP) were also converted to cycloalkanes with a yield of 48.39 wt %, suggesting that the amorphous FeNi-ZrO2 catalyst has a universal catalytic capacity in the HDO reaction of phenolic compounds. |
| Keyword | Amorphous FeNi-ZrO2 Guaiacol Lignin depolymerization product (LDP) Hydrodeoxygenation (HDO) Cycloalkanes |
| DOI | 10.1021/acssuschemeng.0c01457 |
| WOS Keyword | GAS-PHASE HYDRODEOXYGENATION ; MODEL COMPOUNDS ; CATALYTIC HYDRODEOXYGENATION ; CARBON NANOTUBES ; PYROLYSIS OIL ; FE CATALYSTS ; HYDROGENATION ; GUAIACOL ; DEPOLYMERIZATION ; DECOMPOSITION |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51876210] ; Strategic Priority Research Program of the Chinese Academy of Sciences[XDA21060102] ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program[2019TQ05L238] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS Research Area | Chemistry ; Science & Technology - Other Topics ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; Strategic Priority Research Program of the Chinese Academy of Sciences ; Tip-top Scientific and Technical Innovative Youth Talents of Guangdong Special Support Program ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| WOS Subject | Chemistry, Multidisciplinary ; Green & Sustainable Science & Technology ; Engineering, Chemical |
| WOS ID | WOS:000545975600012 |
| Publisher | AMER CHEMICAL SOC |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/27427 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Zhang, Xinghua |
| Affiliation | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Peoples R China 2.Dalian Natl Lab Clean Energy, Dalian 116023, Peoples R China 3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Chen, Qiang,Cai, Chiliu,Zhang, Xinghua,et al. Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel[J]. ACS SUSTAINABLE CHEMISTRY & ENGINEERING,2020,8(25):9335-9345. |
| APA | Chen, Qiang.,Cai, Chiliu.,Zhang, Xinghua.,Zhang, Qi.,Chen, Lungang.,...&Ma, Longlong.(2020).Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel.ACS SUSTAINABLE CHEMISTRY & ENGINEERING,8(25),9335-9345. |
| MLA | Chen, Qiang,et al."Amorphous FeNi-ZrO2-Catalyzed Hydrodeoxygenation of Lignin-Derived Phenolic Compounds to Naphthenic Fuel".ACS SUSTAINABLE CHEMISTRY & ENGINEERING 8.25(2020):9335-9345. |
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