Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system

doi:10.1016/j.fuproc.2019.106161

GIEC OpenIR

	Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system
	Jin, Lele 1,2; Li, Wenzhi 1; Liu, Qiying2 ; Ma, Longlong2 ; Li, Song 2; Liu, Yang 1,2; Zhang, Baikai 1; Zhang, Qi2
	2019-12-15
发表期刊	FUEL PROCESSING TECHNOLOGY
ISSN	0378-3820
卷号	196 页码:10
通讯作者	Li, Wenzhi(liwenzhi@ustc.edu.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn)
摘要	The liquid fuel (made of C-5/C-6 alkanes) was obtained directly from the hydrogenolysis of microcrystalline cellulose (MCC) with Ir-VOx/SiO2 combined with HZSM-5 as the composite catalyst in a biphasic system (n-dodecane + H2O). The performance of the catalyst was investigated by carrying out a series of experiments using various V/Ir molar ratios, catalyst dosages, reaction temperatures, reaction time, hydrogen pressure and substrates. At the optimized conditions, the cellulose was almost completely converted, and at the same time, a high C-5/C-6 yield of 85.1% was obtained at 210 degrees C for 24 h and 6 MPa with the V/Ir molar ratio being 0.13. These results not only proved that Ir-VOx/SiO2 (V/Ir = 0.13) has excellent performance for the hydrogenolysis of MCC to liquid alkanes, but also indicated that vanadium is a good metal promoter for iridium. In addition, it was proven the C-5/C-6 alkanes were obtained via sorbitol through the combined effect of Ir-VOx/SiO2 and HZSM-5.
关键词	Liquid fuel Microcrystalline cellulose Hydrogenolysis
DOI	10.1016/j.fuproc.2019.106161
关键词[WOS]	AQUEOUS-PHASE HYDROGENATION ; LIGNOCELLULOSIC BIOMASS ; TETRAHYDROFURFURYL ALCOHOL ; SELECTIVE HYDROGENATION ; LIQUEFIED FUEL ; LEVULINIC ACID ; SUGAR POLYOLS ; KRAFT LIGNIN ; CORN STOVER ; HYDROGENOLYSIS
收录类别	SCI
语种	英语
资助项目	National Natural Science Foundation of China[51536009] ; National Key Research and Development Program of China[2018YFB1501402] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092]
WOS研究方向	Chemistry ; Energy & Fuels ; Engineering
项目资助者	National Natural Science Foundation of China ; National Key Research and Development Program of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program
WOS类目	Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical
WOS记录号	WOS:000487576700009
出版者	ELSEVIER
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/25698
专题	中国科学院广州能源研究所
通讯作者	Li, Wenzhi; Zhang, Qi
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Jin, Lele,Li, Wenzhi,Liu, Qiying,et al. Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system[J]. FUEL PROCESSING TECHNOLOGY,2019,196:10.
APA	Jin, Lele.,Li, Wenzhi.,Liu, Qiying.,Ma, Longlong.,Li, Song.,...&Zhang, Qi.(2019).Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system.FUEL PROCESSING TECHNOLOGY,196,10.
MLA	Jin, Lele,et al."Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system".FUEL PROCESSING TECHNOLOGY 196(2019):10.