Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system | |
Jin, Lele1,2; Li, Wenzhi1; Liu, Qiying2 ; Ma, Longlong2; Li, Song2; Liu, Yang1,2; Zhang, Baikai1; Zhang, Qi2
| |
| 2019-12-15 | |
| Source Publication | FUEL PROCESSING TECHNOLOGY
 |
| ISSN | 0378-3820 |
| Volume | 196Pages:10 |
| Corresponding Author | Li, Wenzhi(liwenzhi@ustc.edu.cn) ; Zhang, Qi(zhangqi@ms.giec.ac.cn) |
| Abstract | The liquid fuel (made of C-5/C-6 alkanes) was obtained directly from the hydrogenolysis of microcrystalline cellulose (MCC) with Ir-VOx/SiO2 combined with HZSM-5 as the composite catalyst in a biphasic system (n-dodecane + H2O). The performance of the catalyst was investigated by carrying out a series of experiments using various V/Ir molar ratios, catalyst dosages, reaction temperatures, reaction time, hydrogen pressure and substrates. At the optimized conditions, the cellulose was almost completely converted, and at the same time, a high C-5/C-6 yield of 85.1% was obtained at 210 degrees C for 24 h and 6 MPa with the V/Ir molar ratio being 0.13. These results not only proved that Ir-VOx/SiO2 (V/Ir = 0.13) has excellent performance for the hydrogenolysis of MCC to liquid alkanes, but also indicated that vanadium is a good metal promoter for iridium. In addition, it was proven the C-5/C-6 alkanes were obtained via sorbitol through the combined effect of Ir-VOx/SiO2 and HZSM-5. |
| Keyword | Liquid fuel Microcrystalline cellulose Hydrogenolysis |
| DOI | 10.1016/j.fuproc.2019.106161 |
| WOS Keyword | AQUEOUS-PHASE HYDROGENATION ; LIGNOCELLULOSIC BIOMASS ; TETRAHYDROFURFURYL ALCOHOL ; SELECTIVE HYDROGENATION ; LIQUEFIED FUEL ; LEVULINIC ACID ; SUGAR POLYOLS ; KRAFT LIGNIN ; CORN STOVER ; HYDROGENOLYSIS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[51536009] ; National Key Research and Development Program of China[2018YFB1501402] ; Natural Science Foundation of Guangdong Province[2017A030308010] ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program[2017BT01N092] |
| WOS Research Area | Chemistry ; Energy & Fuels ; Engineering |
| Funding Organization | National Natural Science Foundation of China ; National Key Research and Development Program of China ; Natural Science Foundation of Guangdong Province ; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program |
| WOS Subject | Chemistry, Applied ; Energy & Fuels ; Engineering, Chemical |
| WOS ID | WOS:000487576700009 |
| Publisher | ELSEVIER |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/25698 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Li, Wenzhi; Zhang, Qi |
| Affiliation | 1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Anhui, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Jin, Lele,Li, Wenzhi,Liu, Qiying,et al. Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system[J]. FUEL PROCESSING TECHNOLOGY,2019,196:10. |
| APA | Jin, Lele.,Li, Wenzhi.,Liu, Qiying.,Ma, Longlong.,Li, Song.,...&Zhang, Qi.(2019).Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system.FUEL PROCESSING TECHNOLOGY,196,10. |
| MLA | Jin, Lele,et al."Catalytic conversion of cellulose to C-5/C-6 alkanes over Ir-VOx/SO2 combined with HZSM-5 in n-dodecane/water system".FUEL PROCESSING TECHNOLOGY 196(2019):10. |
| Files in This Item: | There are no files associated with this item. | |||||
Items in the repository are protected by copyright, with all rights reserved, unless otherwise indicated.
Edit Comment