Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Kinetic Effects of Ionic Liquids on Methane Hydrate | |
Shen, Xiao-dong1; Zhou, Xue-bing2,3,4,5; Liang, De-qing2,3,4,5 | |
2019-02-01 | |
发表期刊 | ENERGY & FUELS |
ISSN | 0887-0624 |
卷号 | 33期号:2页码:1422-1432 |
通讯作者 | Liang, De-qing(liangdq@ms.giec.ac.cn) |
摘要 | The kinetic effects of several kinds of ionic liquids (ILs) on the formation of methane hydrate were experimentally investigated on both the macroscale and microscale levels. These ILs were 1-ethyl-3-methylimidazolium tetrafluoroborate ([EMIm]-BF4), 1-butyl-3-methylimidazolium tetrafluoroborate ([BMIm]-BF4), 1-butyl-3-methylimidazolium iodide ([BMIm]-I), and N-butyl-N-methylpyrrolidinium tetrafluoroborate ([Py14]-BF4). Formation temperature, max subcooling, induction time, and growth rate of methane gas hydrates were used to evaluate the kinetic effects of ionic liquids in a high-pressure cell and flow loop. As evaluated from the indicator of the formation temperature in the high-pressure cell, the sequence of inhibition performance of ILs was as follows: pure water < 1 wt % [EMIm]-BF4 < 1 wt % PVP < 1 wt % [BMIm]-I < 1 wt % [BMIm]-BF4 < 1 wt % [Py14]-BF4. ILs could not slow the growth rates of methane hydrate effectively and even promote the gas consumption rates irrespective of in a high-pressure cell or flow loop. RXRD spectra showed that ILs could not change the structure of methane hydrate. Cryo-scanning electron microscopy images showed that there was a porous texture of methane hydrate containing ILs. Raman spectra showed that ILs interact with the cages of methane hydrate. |
DOI | 10.1021/acs.energyfuels.8b03108 |
关键词[WOS] | DUAL FUNCTION INHIBITORS ; PHASE-EQUILIBRIA ; CO2 HYDRATE ; DISSOCIATION CONDITIONS ; INDUCTION TIME ; AMINO-ACIDS ; WATER ; SOLVENTS ; RISK ; CHLORIDE |
收录类别 | SCI |
语种 | 英语 |
资助项目 | National Key Research and Development Plan of China[2017YFC0307306] ; National Natural Science Foundation of China[51376182] ; National Natural Science Foundation of China[41473063] ; CAS Program[KGZD-EW-301] ; Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology)[PLC20190605] |
WOS研究方向 | Energy & Fuels ; Engineering |
项目资助者 | National Key Research and Development Plan of China ; National Natural Science Foundation of China ; CAS Program ; Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation (Chengdu University of Technology) |
WOS类目 | Energy & Fuels ; Engineering, Chemical |
WOS记录号 | WOS:000459836800081 |
出版者 | AMER CHEMICAL SOC |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/24636 |
通讯作者 | Liang, De-qing |
作者单位 | 1.Chengdu Univ Technol, State Key Lab Oil & Gas Reservoir Geol & Exploita, Chengdu 610059, Sichuan, Peoples R China 2.Chinese Acad Sci, CAS Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 4.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 5.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Guangdong, Peoples R China |
推荐引用方式 GB/T 7714 | Shen, Xiao-dong,Zhou, Xue-bing,Liang, De-qing. Kinetic Effects of Ionic Liquids on Methane Hydrate[J]. ENERGY & FUELS,2019,33(2):1422-1432. |
APA | Shen, Xiao-dong,Zhou, Xue-bing,&Liang, De-qing.(2019).Kinetic Effects of Ionic Liquids on Methane Hydrate.ENERGY & FUELS,33(2),1422-1432. |
MLA | Shen, Xiao-dong,et al."Kinetic Effects of Ionic Liquids on Methane Hydrate".ENERGY & FUELS 33.2(2019):1422-1432. |
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