GIEC OpenIR
Isothermal Crystallization and Rheology Properties of Isotactic Polypropylene/Bacterial Cellulose Composite
Wang, Bo1,2; Lin, Fu-hua2,3; Li, Xiang-yang3; Zhang, Zhong-wei1; Xue, Xiao-rong1; Liu, Si-xiao1; Ji, Xu-ran1; Yu, Qian1; Yuan, Zheng-qiu2,4; Chen, Xin-de2; Luo, Jun5
2018-11-01
Source PublicationPOLYMERS
ISSN2073-4360
Volume10Issue:11Pages:12
Corresponding AuthorChen, Xin-de(chenxd@ms.giec.ac.cn) ; Luo, Jun(luoj@gtt.net.cn)
AbstractBacterial cellulose (BC) is a new kind of cellulose with great potential in enhancing preparation of isotactic Polypropylene (iPP) composites, which have been found with excellent performance. However, the interface compatibility between BC and iPP is poor. In this study, iPP/BC composites were prepared by solution mixing. Esterification modified BC (CO) and Maleic anhydride grafted polypropylene (MAPP) added as a compatibilizer was both used to improve the interfacial compatibility of the iPP/BC composites. The rheology and isothermal crystallization behavior of the composites was tested and discussed. The result shows that the complex viscosity and storage modulus of the composite significantly increase in the rule iPP, iPP/BC2, iPP/CO2, and M-iPP/BC3, which indicates that the compatibility of the composite increases as this rule. According to the isothermal crystallization kinetics result, the crystal growth mode of iPP was not affected by the addition of BC and the interfacial compatibility. The spherulite growth rate of the iPP/BC composite increases with increasing crystallization temperature. Especially, the value decreases as the same rule with the complex viscosity and storage modulus of the composite at the same isothermal crystallization temperature. These results suggest that the interface compatibility of iPP/BC composites is greatly improved and the interface compatibility of the M-iPP/BC3 is better than the iPP/CO2.
KeywordIsotactic polypropylene bacterial cellulose rheology isothermal crystallization
DOI10.3390/polym10111284
WOS KeywordMECHANICAL-PROPERTIES ; MORPHOLOGY ; BEHAVIOR ; NANOCOMPOSITES ; BLENDS ; GROWTH ; RATES
Indexed BySCI
Language英语
Funding ProjectScientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi[201802087] ; CAS Key Laboratory of Renewable Energy[Y707k91001] ; Doctoral startup project of Taiyuan University of Science and Technology[20162013] ; National Natural Science Foundation of China[51303181]
WOS Research AreaPolymer Science
Funding OrganizationScientific and Technologial Innovation Programs of Higher Education Institutions in Shanxi ; CAS Key Laboratory of Renewable Energy ; Doctoral startup project of Taiyuan University of Science and Technology ; National Natural Science Foundation of China
WOS SubjectPolymer Science
WOS IDWOS:000454456800106
PublisherMDPI
Citation statistics
Cited Times:21[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/24442
Collection中国科学院广州能源研究所
Corresponding AuthorChen, Xin-de; Luo, Jun
Affiliation1.Taiyuan Univ Sci & Technol, Sch Chem & Biol Engn, Taiyuan 030024, Shanxi, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Shanxi Prov Inst Chem Ind, Taiyuan 030021, Shanxi, Peoples R China
4.Hunan Univ Sci & Technol, Sch Chem & Chem Engn, Xiang Tan 411201, Peoples R China
5.Guangzhou Fibre Prod Testing & Res Inst, Guangzhou 510220, Guangdong, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Wang, Bo,Lin, Fu-hua,Li, Xiang-yang,et al. Isothermal Crystallization and Rheology Properties of Isotactic Polypropylene/Bacterial Cellulose Composite[J]. POLYMERS,2018,10(11):12.
APA Wang, Bo.,Lin, Fu-hua.,Li, Xiang-yang.,Zhang, Zhong-wei.,Xue, Xiao-rong.,...&Luo, Jun.(2018).Isothermal Crystallization and Rheology Properties of Isotactic Polypropylene/Bacterial Cellulose Composite.POLYMERS,10(11),12.
MLA Wang, Bo,et al."Isothermal Crystallization and Rheology Properties of Isotactic Polypropylene/Bacterial Cellulose Composite".POLYMERS 10.11(2018):12.
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