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Enhanced Electrochemical Properties of Gel Polymer Electrolyte with Hybrid Copolymer of Organic Palygorskite and Methyl Methacrylate
Tian, Lanlan1,2,3,4,5; Xiong, Lian1,2,3,4; Chen, Xuefang1,2,3,4; Guo, Haijun1,2,3,4; Zhang, Hairong1,2,3,4; Chen, Xinde1,2,3,4
2018-10-01
Source PublicationMATERIALS
ISSN1996-1944
Volume11Issue:10Pages:9
Corresponding AuthorZhang, Hairong(cxd_cxd@hotmail.com) ; Chen, Xinde(chenxue_228@126.com)
AbstractGel polymer electrolyte (GPE) is widely considered as a promising safe lithium-ion battery material compared to conventional organic liquid electrolyte, which is linked to a greater risk of corrosive liquid leakage, spontaneous combustion, and explosion. GPE contains polymers, lithium salts, and liquid electrolyte, and inorganic nanoparticles are often used as fillers to improve electrochemical performance. However, such composite polymer electrolytes are usually prepared by means of blending, which can impact on the compatibility between the polymer and filler. In this study, the hybrid copolymer poly (organic palygorskite-co-methyl methacrylate) (poly(OPal-MMA)) is synthesized using organic palygorskite (OPal) and MMA as raw materials. The poly(OPal-MMA) gel electrolyte exhibits an ionic conductivity of 2.94 x 10(-3) S/cm at 30 degrees C. The Li/poly(OPal-MMA) electrolyte/LiFePO4 cell shows a wide electrochemical window (approximately 4.7 V), high discharge capacity (146.36 mAh/g), and a low capacity-decay rate (0.02%/cycle).
Keywordlithium polymer battery poly (organic palygorskite-co-methyl methacrylate) microporous polymer electrolyte
DOI10.3390/ma11101814
WOS KeywordLITHIUM-ION BATTERIES ; EMULSION POLYMERIZATION ; SOLID-ELECTROLYTE ; PMMA ; TRANSPORT ; MEMBRANES ; LIQUID ; NANOCOMPOSITES ; CONDUCTIVITY ; EFFICIENCY
Indexed BySCI
Language英语
Funding ProjectProject of Jiangsu Province Science and Technology[BE2016125] ; tender project of HuaiAn[HAZC2018010036] ; Open Foundation of Xuyi Center of Attapulgite Applied Technology Research Development and Industrialization, Chinese Academy of Sciences[201604]
WOS Research AreaMaterials Science
Funding OrganizationProject of Jiangsu Province Science and Technology ; tender project of HuaiAn ; Open Foundation of Xuyi Center of Attapulgite Applied Technology Research Development and Industrialization, Chinese Academy of Sciences
WOS SubjectMaterials Science, Multidisciplinary
WOS IDWOS:000448658400028
PublisherMDPI
Citation statistics
Cited Times:16[WOS]   [WOS Record]     [Related Records in WOS]
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/24153
Collection中国科学院广州能源研究所
Corresponding AuthorZhang, Hairong; Chen, Xinde
Affiliation1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Chinese Acad Sci, Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China
4.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China
5.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
Tian, Lanlan,Xiong, Lian,Chen, Xuefang,et al. Enhanced Electrochemical Properties of Gel Polymer Electrolyte with Hybrid Copolymer of Organic Palygorskite and Methyl Methacrylate[J]. MATERIALS,2018,11(10):9.
APA Tian, Lanlan,Xiong, Lian,Chen, Xuefang,Guo, Haijun,Zhang, Hairong,&Chen, Xinde.(2018).Enhanced Electrochemical Properties of Gel Polymer Electrolyte with Hybrid Copolymer of Organic Palygorskite and Methyl Methacrylate.MATERIALS,11(10),9.
MLA Tian, Lanlan,et al."Enhanced Electrochemical Properties of Gel Polymer Electrolyte with Hybrid Copolymer of Organic Palygorskite and Methyl Methacrylate".MATERIALS 11.10(2018):9.
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