Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene | |
Li, Zhongcheng1,2; Zhang, Deliang1; Ma, Jiaojiao1; Wang, Debao1; Xie, Congxia1 | |
2018-02-15 | |
Source Publication | MATERIALS LETTERS
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ISSN | 0167-577X |
Volume | 213Pages:350-353 |
Corresponding Author | Li, Zhongcheng(zhongchengli@qust.edu.cn) ; Wang, Debao(swang@qingdaonews.com) ; Xie, Congxia(xiecongxia@126.com) |
Abstract | MoS2 microflowers with the size of 3.9-5.8 mu m in diameter, which is constructed by nanosheets, are hydrothermally synthesized using sodium diethyldithiocarbamate trihydrate as the sulfur source. Studies on the hydrothermal process reveal that the temperature plays crucial roles in determining the crystal phase of MoS2. It is found that the higher temperature favors the reduction of Mo (VI) to Mo (IV). The obtained MoS2 microflowers are highly active and selective for hydrogenation of nitrobenzene into aniline. Compared with commercial MoS2, the higher percentage of coordinative unsaturated Mo sites on MoS2 microflowers offer a relatively higher catalytic activity. (c) 2017 Elsevier B.V. All rights reserved. |
Keyword | MoS2 microflowers Coordinative unsaturated Mo sites Nitrobenzene hydrogenation Functional Microstructure |
DOI | 10.1016/j.matlet.2017.11.042 |
WOS Keyword | TEMPERATURE-PROGRAMMED REDUCTION ; NITROARENES ; HYDRODESULFURIZATION ; NANOPARTICLES ; CATALYSTS |
Indexed By | SCI |
Language | 英语 |
Funding Project | National Natural Science Foundation of China[21503117] ; National Natural Science Foundation of China[31270615] ; project of Shandong Province Higher Educational Science and Technology Program[J16LC16] ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences[Y607k81001] ; Natural Science Foundation of Shandong Province[ZR2017MB034] |
WOS Research Area | Materials Science ; Physics |
Funding Organization | National Natural Science Foundation of China ; project of Shandong Province Higher Educational Science and Technology Program ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province |
WOS Subject | Materials Science, Multidisciplinary ; Physics, Applied |
WOS ID | WOS:000419049300088 |
Publisher | ELSEVIER SCIENCE BV |
Citation statistics | |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/22559 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | Li, Zhongcheng; Wang, Debao; Xie, Congxia |
Affiliation | 1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,et al. Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene[J]. MATERIALS LETTERS,2018,213:350-353. |
APA | Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,Wang, Debao,&Xie, Congxia.(2018).Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene.MATERIALS LETTERS,213,350-353. |
MLA | Li, Zhongcheng,et al."Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene".MATERIALS LETTERS 213(2018):350-353. |
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