Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene

doi:10.1016/j.matlet.2017.11.042

GIEC OpenIR

	Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene
	Li, Zhongcheng 1,2; Zhang, Deliang 1; Ma, Jiaojiao 1; Wang, Debao 1; Xie, Congxia 1
	2018-02-15
Source Publication	MATERIALS LETTERS
ISSN	0167-577X
Volume	213 Pages:350-353
Corresponding Author	Li, Zhongcheng(zhongchengli@qust.edu.cn) ; Wang, Debao(swang@qingdaonews.com) ; Xie, Congxia(xiecongxia@126.com)
Abstract	MoS2 microflowers with the size of 3.9-5.8 mu m in diameter, which is constructed by nanosheets, are hydrothermally synthesized using sodium diethyldithiocarbamate trihydrate as the sulfur source. Studies on the hydrothermal process reveal that the temperature plays crucial roles in determining the crystal phase of MoS2. It is found that the higher temperature favors the reduction of Mo (VI) to Mo (IV). The obtained MoS2 microflowers are highly active and selective for hydrogenation of nitrobenzene into aniline. Compared with commercial MoS2, the higher percentage of coordinative unsaturated Mo sites on MoS2 microflowers offer a relatively higher catalytic activity. (c) 2017 Elsevier B.V. All rights reserved.
Keyword	MoS2 microflowers Coordinative unsaturated Mo sites Nitrobenzene hydrogenation Functional Microstructure
DOI	10.1016/j.matlet.2017.11.042
WOS Keyword	TEMPERATURE-PROGRAMMED REDUCTION ; NITROARENES ; HYDRODESULFURIZATION ; NANOPARTICLES ; CATALYSTS
Indexed By	SCI
Language	英语
Funding Project	National Natural Science Foundation of China[21503117] ; National Natural Science Foundation of China[31270615] ; project of Shandong Province Higher Educational Science and Technology Program[J16LC16] ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences[Y607k81001] ; Natural Science Foundation of Shandong Province[ZR2017MB034]
WOS Research Area	Materials Science ; Physics
Funding Organization	National Natural Science Foundation of China ; project of Shandong Province Higher Educational Science and Technology Program ; Key Laboratory of Renewable Energy, Chinese Academy of Sciences ; Natural Science Foundation of Shandong Province
WOS Subject	Materials Science, Multidisciplinary ; Physics, Applied
WOS ID	WOS:000419049300088
Publisher	ELSEVIER SCIENCE BV
Citation statistics	Cited Times:22[WOS] [WOS Record] [Related Records in WOS]
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/22559
Collection	中国科学院广州能源研究所
Corresponding Author	Li, Zhongcheng; Wang, Debao; Xie, Congxia
Affiliation	1.Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, State Key Lab Base Ecochem Engn, Qingdao 266042, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
First Author Affilication	GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation GB/T 7714	Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,et al. Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene[J]. MATERIALS LETTERS,2018,213:350-353.
APA	Li, Zhongcheng,Zhang, Deliang,Ma, Jiaojiao,Wang, Debao,&Xie, Congxia.(2018).Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene.MATERIALS LETTERS,213,350-353.
MLA	Li, Zhongcheng,et al."Fabrication of MoS2 microflowers for hydrogenation of nitrobenzene".MATERIALS LETTERS 213(2018):350-353.

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