Conversion of Cellulose to 5-Hydroxymethylfurfural in WaterTetrahydrofuran and Byproducts Identification

GIEC OpenIR

	Conversion of Cellulose to 5-Hydroxymethylfurfural in WaterTetrahydrofuran and Byproducts Identification
	Shi Ning; Liu Qiying; Wang Tiejun; Zhang Qi; Tu Junling; Ma Longlong
	2014
Source Publication	Chinese Journal of Chemical Physics
ISSN	1674-0068
Volume	27 Issue:6 Pages:711
Abstract	Conversion of cellulose into platform chemical 5-hydroxymethylfurfural (HMF) in watertetrahydrofuran (THF) co-solvents under acidic condition was studied. 38.6% of HMF was obtained with low cellulose concentration of 2.4wt%, but levulinic acid (LA) and solid humins became the main products with high cellulose concentration. The soluble byproducts were analyzed by high performance liquid chromatography/multiple stage tandem mass spectrometry, and chemicals with formula of C_9H16O4, C10H14O4, C11H12O4,C12H10O5 and C12H16O8 were detected. THF could participate in the reaction via ring-opening into 1,4butanediol followed by esterification with LA into C9H6O4 or etherification with HMF into C10H14O4. C11H12O4 was formed by esterification of HMF with LA, C12H10O5 was formed by self-etherification of HMF, while C12H16O8 was formed by acetalization of HMF with glucose. Self-etherification of HMF and etherification of HMF with 1,4-butanediol were identified as two main side reactions.
Language	英语
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/21953
Collection	中国科学院广州能源研究所
Affiliation	中国科学院广州能源研究所
First Author Affilication	GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation GB/T 7714	Shi Ning,Liu Qiying,Wang Tiejun,et al. Conversion of Cellulose to 5-Hydroxymethylfurfural in WaterTetrahydrofuran and Byproducts Identification[J]. Chinese Journal of Chemical Physics,2014,27(6):711.
APA	Shi Ning,Liu Qiying,Wang Tiejun,Zhang Qi,Tu Junling,&Ma Longlong.(2014).Conversion of Cellulose to 5-Hydroxymethylfurfural in WaterTetrahydrofuran and Byproducts Identification.Chinese Journal of Chemical Physics,27(6),711.
MLA	Shi Ning,et al."Conversion of Cellulose to 5-Hydroxymethylfurfural in WaterTetrahydrofuran and Byproducts Identification".Chinese Journal of Chemical Physics 27.6(2014):711.

Files in This Item:
There are no files associated with this item.

If you have any objections to this item, please fill out the form below and the administrator will contact you as soon as possible.
Content:
Email：	*
Institution:
Verification Code:	Refresh

Any comments and suggestions are welcomed.
Title:	*
Content:
Email：	*
Verification Code:	Refresh

中国科学院广州能源研究所机构知识库