Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
sulfidebasedionicliquidelectrolytewideningtheapplicationtemperaturerangeofquantumdotsensitizedsolarcells | |
Shi Jifu1; Huang Qizhang1; Wan Qingcui1; Xu Xueqing1; Li Chunsheng2; Xu Gang1 | |
2016 | |
Source Publication | 物理化学学报 |
ISSN | 1000-6818 |
Volume | 32Issue:4Pages:822 |
Abstract | We report the preparation and application of a 1-methyl-3-propylimidazolium sulfide-based ionic liquid electrolyte for quantum-dot-sensitized solar cells. By optimizing the concentrations of S and Na_2S, a considerable conductivity of 12.96 mS?cm~(-1) is achieved at 25 °C. Differential scanning calorimetry indicates that the glass transition temperature of the electrolyte is -85 ° C. The quantum-dot- sensitized solar cell assembled with this ionic liquid electrolyte displays a high energy conversion efficiency (η) of 3.03% at 25 °C, which is comparable to the efficiency of quantum-dot-sensitized solar cells using a water-based polysulfide electrolyte (η = 3.34%). Due to the favorable thermal properties of this ionic liquid electrolyte (lower glass transition temperature and nonvolatility at higher temperatures), the quantum-dot-sensitized solar cell maintains satisfactory η even at -20 °C (η = 2.32%) and 80 °C (η = 1.90%), which is superior to the cell using the water- based polysulfide electrolyte. |
Language | 英语 |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/20080 |
Collection | 中国科学院广州能源研究所 |
Affiliation | 1.中国科学院广州能源研究所 2.华北理工大学 |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | Shi Jifu,Huang Qizhang,Wan Qingcui,et al. sulfidebasedionicliquidelectrolytewideningtheapplicationtemperaturerangeofquantumdotsensitizedsolarcells[J]. 物理化学学报,2016,32(4):822. |
APA | Shi Jifu,Huang Qizhang,Wan Qingcui,Xu Xueqing,Li Chunsheng,&Xu Gang.(2016).sulfidebasedionicliquidelectrolytewideningtheapplicationtemperaturerangeofquantumdotsensitizedsolarcells.物理化学学报,32(4),822. |
MLA | Shi Jifu,et al."sulfidebasedionicliquidelectrolytewideningtheapplicationtemperaturerangeofquantumdotsensitizedsolarcells".物理化学学报 32.4(2016):822. |
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