anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries

GIEC OpenIR

	anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries
	Zhao Xinyue 1; Wang Jinglun1 ; Luo Hao1 ; Yao Hurong 2; Ouyang Chuying 2; Zhang Lingzhi1
	2016
发表期刊	journalofzhejianguniversityscienceaappliedphysicsengineering
ISSN	1673-565X
卷号	17 期号:2 页码:155
摘要	A novel organosilicon-based ionic plastic crystal, N,N,N,-diethylmethyl-N-(trimethylsilyl)methylammonium bistrifluoromethane sulfonimide (DTMATFSI) was designed and synthesized as solid-state electrolyte for lithium-ion batteries. The chemical structure and the physical and electrochemical properties were characterized in detail. The ionic conductivity of DTMATFSI was improved significantly by doping with lithium oxalyldifluoroborate (LiODFB) and propylene carbonate (PC). An optimized plastic crystal composite (DTMATFSI:LiODFB:PC=8:1:1 in molar ratio) as a solid-state electrolyte exhibited a decent cycling stability in LiFePO_4/Li half-cell, with a specific discharge capacity of 144 mA·h/g and capacity retention of 94% after 50 cycles at C/20.
语种	英语
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/19657
专题	中国科学院广州能源研究所
作者单位	1.中国科学院广州能源研究所 2.江西师范大学
第一作者单位	中国科学院广州能源研究所
推荐引用方式 GB/T 7714	Zhao Xinyue,Wang Jinglun,Luo Hao,et al. anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries[J]. journalofzhejianguniversityscienceaappliedphysicsengineering,2016,17(2):155.
APA	Zhao Xinyue,Wang Jinglun,Luo Hao,Yao Hurong,Ouyang Chuying,&Zhang Lingzhi.(2016).anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries.journalofzhejianguniversityscienceaappliedphysicsengineering,17(2),155.
MLA	Zhao Xinyue,et al."anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries".journalofzhejianguniversityscienceaappliedphysicsengineering 17.2(2016):155.