anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries

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	anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries
	Zhao Xinyue 1; Wang Jinglun1 ; Luo Hao1 ; Yao Hurong 2; Ouyang Chuying 2; Zhang Lingzhi1
	2016
Source Publication	journalofzhejianguniversityscienceaappliedphysicsengineering
ISSN	1673-565X
Volume	17 Issue:2 Pages:155
Abstract	A novel organosilicon-based ionic plastic crystal, N,N,N,-diethylmethyl-N-(trimethylsilyl)methylammonium bistrifluoromethane sulfonimide (DTMATFSI) was designed and synthesized as solid-state electrolyte for lithium-ion batteries. The chemical structure and the physical and electrochemical properties were characterized in detail. The ionic conductivity of DTMATFSI was improved significantly by doping with lithium oxalyldifluoroborate (LiODFB) and propylene carbonate (PC). An optimized plastic crystal composite (DTMATFSI:LiODFB:PC=8:1:1 in molar ratio) as a solid-state electrolyte exhibited a decent cycling stability in LiFePO_4/Li half-cell, with a specific discharge capacity of 144 mA·h/g and capacity retention of 94% after 50 cycles at C/20.
Language	英语
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/19657
Collection	中国科学院广州能源研究所
Affiliation	1.中国科学院广州能源研究所 2.江西师范大学
First Author Affilication	GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation GB/T 7714	Zhao Xinyue,Wang Jinglun,Luo Hao,et al. anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries[J]. journalofzhejianguniversityscienceaappliedphysicsengineering,2016,17(2):155.
APA	Zhao Xinyue,Wang Jinglun,Luo Hao,Yao Hurong,Ouyang Chuying,&Zhang Lingzhi.(2016).anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries.journalofzhejianguniversityscienceaappliedphysicsengineering,17(2),155.
MLA	Zhao Xinyue,et al."anovelorganosiliconbasedionicplasticcrystalassolidstateelectrolyteforlithiumionbatteries".journalofzhejianguniversityscienceaappliedphysicsengineering 17.2(2016):155.

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