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predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions
Liu Yansheng1; Hu Yufeng1; Zeng Peng1; Fan Shuanshi2; Liang Deqing2; Liu Zhichang1
2006
Source Publicationchinesejournalofchemicalengineering
ISSN1004-9541
Volume14Issue:4Pages:494
AbstractThe simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1:1, 1:2, and 1:3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCL2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii's rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer's equation.
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/19297
Collection中国科学院广州能源研究所
Affiliation1.China University of Petroleum,High Pressure Fluid Phase Behavior & Property Research Laboratory
2.中国科学院广州能源研究所
Recommended Citation
GB/T 7714
Liu Yansheng,Hu Yufeng,Zeng Peng,et al. predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions[J]. chinesejournalofchemicalengineering,2006,14(4):494.
APA Liu Yansheng,Hu Yufeng,Zeng Peng,Fan Shuanshi,Liang Deqing,&Liu Zhichang.(2006).predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions.chinesejournalofchemicalengineering,14(4),494.
MLA Liu Yansheng,et al."predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions".chinesejournalofchemicalengineering 14.4(2006):494.
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