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predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions
Liu Yansheng1; Hu Yufeng1; Zeng Peng1; Fan Shuanshi2; Liang Deqing2; Liu Zhichang1
2006
发表期刊chinesejournalofchemicalengineering
ISSN1004-9541
卷号14期号:4页码:494
摘要The simple equation relating the activity coefficient of each solute in mixed electrolyte solution to its value in binary solutions under isopiestic equilibrium was tested by comparison with the experimental data for the 18 electrolyte solutions consisting of 1:1, 1:2, and 1:3 electrolytes. The isopiestic measurements were made on the quaternary system BaCl2-NH4Br-NaI-H2O and its ternary subsystems NaI-NH4Br-H2O, NaI-BaCL2-H2O, and NH4Br-BaCl2-H2O at 298.15K. The results were used to test the applicability of the Zdanovskii's rule to the mixed electrolyte solutions which contain no common ions, and the agreement is excellent. The activity coefficients of the solutes in the above quaternary and ternary systems calculated from the above-mentioned simple equation are in good agreement with the Pitzer's equation.
语种英语
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/19297
专题中国科学院广州能源研究所
作者单位1.China University of Petroleum,High Pressure Fluid Phase Behavior & Property Research Laboratory
2.中国科学院广州能源研究所
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GB/T 7714
Liu Yansheng,Hu Yufeng,Zeng Peng,et al. predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions[J]. chinesejournalofchemicalengineering,2006,14(4):494.
APA Liu Yansheng,Hu Yufeng,Zeng Peng,Fan Shuanshi,Liang Deqing,&Liu Zhichang.(2006).predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions.chinesejournalofchemicalengineering,14(4),494.
MLA Liu Yansheng,et al."predictionofactivitycoefficientsformixedaqueouselectrolytesolutionsfromthedataoftheirbinarysolutions".chinesejournalofchemicalengineering 14.4(2006):494.
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