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phasediagrampredictionofsystemsmnno32mno3nh2omcamgandliwithmodifiedbetmodel
Zeng Dewen1; Fan Shuanshi2; Chen Sihai1
2004
发表期刊transactionsofnonferrousmetalssocietyofchina
ISSN1003-6326
卷号14期号:6页码:1192
摘要BET-model parameters for the binary system Mn(NO3 )2-H2 O were obtained by fitting experimental water activities at 298.15 K. The values obtained in this work were compared to those fitted previously for the systems Ca(NO3)2-H2O and Zn(NO3)2-H2O, showing reasonable agreement. With the model parameters fitted at 298 K,the vapor pressure of the saturated solution for the phases Mn(NO3 )2 · 6 H2 O and Mn(NO3 )2 · 4 H2 O were predicted and shows quite good agreement with the experimental values. The phase diagram of the Mn(NO2 )2-H2O system reproduced by the BET model shows smaller deviation from the experimental data than that by the extended UNIQUAC model. The ternary phase diagrams of the systems Me(NO3)n-Mn(NO3)2-H2O (Me= Mg, Ca and Li) are predicted with the binary model parameter and compared with available experimental data. The predicted eutectic compositions were given as possible heat storage materials.
语种英语
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/19205
专题中国科学院广州能源研究所
作者单位1.College of Chemistry and Chemical Engineering,Hunan University
2.中国科学院广州能源研究所
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GB/T 7714
Zeng Dewen,Fan Shuanshi,Chen Sihai. phasediagrampredictionofsystemsmnno32mno3nh2omcamgandliwithmodifiedbetmodel[J]. transactionsofnonferrousmetalssocietyofchina,2004,14(6):1192.
APA Zeng Dewen,Fan Shuanshi,&Chen Sihai.(2004).phasediagrampredictionofsystemsmnno32mno3nh2omcamgandliwithmodifiedbetmodel.transactionsofnonferrousmetalssocietyofchina,14(6),1192.
MLA Zeng Dewen,et al."phasediagrampredictionofsystemsmnno32mno3nh2omcamgandliwithmodifiedbetmodel".transactionsofnonferrousmetalssocietyofchina 14.6(2004):1192.
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