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流光电晕裂解焦油模型化合物的动力学模拟
徐彬1; 谢建军1; 阴秀丽1; 邓官垒2; 吴创之1; 闫克平2
2018
Source Publication太阳能学报
ISSN0254-0096
Volume39Issue:11Pages:3178
Abstract选用萘、苯酚为焦油模型化合物,构建萘、苯酚裂解的化学动力学模型.考察初始浓度、温度及水分对萘、苯酚裂解特性的影响;并对苯酚进行生成速率分析和敏感性分析,得到其裂解路径.结果表明:计算值与实验值较好吻合;200 ℃时萘、苯酚裂解率从90%提高至99%,能量密度增加70%;在200~500 ℃范围内,注入能量密度相同时,萘裂解率在约400 ℃时达最大值,而苯酚裂解率随温度增高而逐渐上升;在200 ℃时H_2O的加入对于裂解所需能量密度无显著影响;苯酚与O、H自由基的反应是其主要的裂解路径.
Language英语
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/19043
Collection中国科学院广州能源研究所
Affiliation1.中国科学院广州能源研究所
2.浙江大学
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
徐彬,谢建军,阴秀丽,等. 流光电晕裂解焦油模型化合物的动力学模拟[J]. 太阳能学报,2018,39(11):3178.
APA 徐彬,谢建军,阴秀丽,邓官垒,吴创之,&闫克平.(2018).流光电晕裂解焦油模型化合物的动力学模拟.太阳能学报,39(11),3178.
MLA 徐彬,et al."流光电晕裂解焦油模型化合物的动力学模拟".太阳能学报 39.11(2018):3178.
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