Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Simply packaging Ni nanoparticles inside SBA-15 channels by co-impregnation for dry reforming of methane | |
Qiu, Songbai ; Zhang, Qiao ; Lv, Wei ; Wang, Tiejun ; Zhang, Qi ; Ma, Longlong | |
2017 | |
发表期刊 | RSC ADVANCES |
卷号 | 7页码:24551-24560 |
其他摘要 | The highly dispersed Ni nanoparticles inside SBA-15 channels (Ni@ SBA- 15) were synthesized simply by co-impregnation using ethylene glycol (EG). During co-impregnation, the EG additive in the metal nitrate aqueous solution could successfully deliver and package the nickel species into the channels of mesoporous SBA-15. The characterization results suggest that drying after impregnation plays a critical role in the distribution of the precursor. Compared with conventional impregnation, redistribution and agglomeration of the Ni precursor were efficiently avoided due to the lower surface tension and high viscosity of the concentrated solution during drying, and super-small Ni nanoparticles with higher dispersions and narrow particle size distributions were predominantly confined over the internal surface of mesoporous channels instead of its external surface. The Ni@ SBA- 15 catalyst using co-impregnation demonstrated excellent sintering-resistance and stability in the dry reforming of methane due to its strong metal-support interaction and the confined location of Ni nanoparticles. |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/16755 |
专题 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Qiu, Songbai,Zhang, Qiao,Lv, Wei,et al. Simply packaging Ni nanoparticles inside SBA-15 channels by co-impregnation for dry reforming of methane[J]. RSC ADVANCES,2017,7:24551-24560. |
APA | Qiu, Songbai,Zhang, Qiao,Lv, Wei,Wang, Tiejun,Zhang, Qi,&Ma, Longlong.(2017).Simply packaging Ni nanoparticles inside SBA-15 channels by co-impregnation for dry reforming of methane.RSC ADVANCES,7,24551-24560. |
MLA | Qiu, Songbai,et al."Simply packaging Ni nanoparticles inside SBA-15 channels by co-impregnation for dry reforming of methane".RSC ADVANCES 7(2017):24551-24560. |
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