Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium

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	Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium
	Zheng, Yuying ; He, Peishan ; Fang, Yanxiong ; Yang, Xu ; Liang, Huagen
	2017
Source Publication	RSC ADVANCES
Volume	7 Pages:31582-31587
Other Abstract	Selective hydrogenation of phenol is of great significant for the production of Nylon 6. Herein, highly efficient and stable Ir promoted Pt catalysts for the hydrogenation of phenol are prepared by deposition of Pt-Ir nanoparticles onto hollow mesoporous silica spheres (HMSs) through a facile wet-impregnation and H-2 reduction method. The obtained PtIr/HMS catalyst with Ir/Pt molar ratio of 0.1 shows a highest hydrogenation rate of 4255 mmol h(-1) gPt(-1) with cyclohexanone selectivity of 85% at 50 degrees C and 0.5 MPa of pH(2), which is 3 times and 8.6 times higher than that of the mono Pt/HMS catalyst and commercial Pt catalyst, respectively. The trace addition of Ir promoter essentially contributes to the enhanced hydrogenation activity by improving the metal dispersion of Pt nanoparticles and promoting the charge transfer between the Pt and Ir. This work provides an effective protocol in developing high performance catalysts for phenol hydrogenation under mild reaction conditions.
Document Type	期刊论文
Identifier	http://ir.giec.ac.cn/handle/344007/16750
Collection	中国科学院广州能源研究所
Recommended Citation GB/T 7714	Zheng, Yuying,He, Peishan,Fang, Yanxiong,et al. Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium[J]. RSC ADVANCES,2017,7:31582-31587.
APA	Zheng, Yuying,He, Peishan,Fang, Yanxiong,Yang, Xu,&Liang, Huagen.(2017).Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium.RSC ADVANCES,7,31582-31587.
MLA	Zheng, Yuying,et al."Hollow mesoporous silica supported PtIr bimetal catalysts for selective hydrogenation of phenol: significant promotion effect of iridium".RSC ADVANCES 7(2017):31582-31587.

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