Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
| Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents | |
Guo, Haijun1,2,3,4,5; Zhang, Hairong1,2,3,4; Tang, Weichao1,2,3,4; Wang, Can1,2,3,4; Huang, Chao1,2,3,4; Chen, Peili1,2,3; Chen, Xinde1,2,3,4 ; Ouyang, Xinping5
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| 2017 | |
| Source Publication | BIORESOURCES
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| ISSN | 1930-2126 |
| Volume | 12Issue:4Pages:8755-8774 |
| Corresponding Author | Chen, Xinde(cxd_cxd@hotmail.com) |
| Abstract | The catalytic hydrogenation of furfural was studied over a series of Ni-B, Co-B, and Ni-Co-B amorphous alloy catalysts that were prepared by the chemical reduction method using KBH4 and NaBH4 as reducing agents. These catalysts were characterized by N-2 adsorption/desorption, XRD, XPS, FE-SEM, and TEM. The results showed that NaBH4 had a much stronger reduction ability to enhance the surface concentration of the metallic active sites for furfural hydrogenation and electron transfer capability, leading to much higher hydrogenation activity. In the Ni-Co-B amorphous alloy catalyst, the equilibrium between the isolated Ni-B/Co-B active sites and the combined Ni-Co-B active sites was important in regulating furfural conversion and products distribution. |
| Keyword | Furfural hydrogenation Ni-Co-B amorphous alloy Reducing agent Synergistic effect Electron transfer capability |
| DOI | 10.15376/biores.12.4.8755-8774 |
| WOS Keyword | LIQUID-PHASE HYDROGENATION ; PORE-SIZE DISTRIBUTION ; NI-B ; CO-B ; SELECTIVE HYDROGENATION ; CHEMICAL-REDUCTION ; ALCOHOL ; CONVERSION ; BOROHYDRIDE ; HYDROLYSIS |
| Indexed By | SCI |
| Language | 英语 |
| Funding Project | National Natural Science Foundation of China[21406229] ; Project of Jiangsu Province Science and Technology[BE2014101] ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development[Y709jh1001] |
| WOS Research Area | Materials Science |
| Funding Organization | National Natural Science Foundation of China ; Project of Jiangsu Province Science and Technology ; Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development |
| WOS Subject | Materials Science, Paper & Wood |
| WOS ID | WOS:000422879900130 |
| Publisher | NORTH CAROLINA STATE UNIV DEPT WOOD & PAPER SCI |
| Citation statistics | |
| Document Type | 期刊论文 |
| Identifier | http://ir.giec.ac.cn/handle/344007/16737 |
| Collection | 中国科学院广州能源研究所 |
| Corresponding Author | Chen, Xinde |
| Affiliation | 1.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 2.Guangdong Prov Key Lab New & Renewable Energy Res, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China 4.Chinese Acad Sci, Guangzhou Inst Energy Convers, R&D Ctr Xuyi Attapulgite Appl Technol, Xuyi 211700, Peoples R China 5.South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Guangdong, Peoples R China |
| First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
| Recommended Citation GB/T 7714 | Guo, Haijun,Zhang, Hairong,Tang, Weichao,et al. Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents[J]. BIORESOURCES,2017,12(4):8755-8774. |
| APA | Guo, Haijun.,Zhang, Hairong.,Tang, Weichao.,Wang, Can.,Huang, Chao.,...&Ouyang, Xinping.(2017).Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents.BIORESOURCES,12(4),8755-8774. |
| MLA | Guo, Haijun,et al."Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents".BIORESOURCES 12.4(2017):8755-8774. |
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