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Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents
Guo, Haijun ; Zhang, Hairong ; Tang, Weichao ; Wang, Can ; Huang, Chao ; Chen, Peili ; Chen, Xinde ; Ouyang, Xinping
2017
Source PublicationBIORESOURCES
Volume12Pages:8755-8774
Other AbstractThe catalytic hydrogenation of furfural was studied over a series of Ni-B, Co-B, and Ni-Co-B amorphous alloy catalysts that were prepared by the chemical reduction method using KBH4 and NaBH4 as reducing agents. These catalysts were characterized by N-2 adsorption/desorption, XRD, XPS, FE-SEM, and TEM. The results showed that NaBH4 had a much stronger reduction ability to enhance the surface concentration of the metallic active sites for furfural hydrogenation and electron transfer capability, leading to much higher hydrogenation activity. In the Ni-Co-B amorphous alloy catalyst, the equilibrium between the isolated Ni-B/Co-B active sites and the combined Ni-Co-B active sites was important in regulating furfural conversion and products distribution.
KeywordFurfural hydrogenation Ni-Co-B amorphous alloy Reducing agent Synergistic effect Electron transfer capability
WOS IDWOS:000422879900130
Citation statistics
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/16737
Collection中国科学院广州能源研究所
Recommended Citation
GB/T 7714
Guo, Haijun,Zhang, Hairong,Tang, Weichao,et al. Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents[J]. BIORESOURCES,2017,12:8755-8774.
APA Guo, Haijun.,Zhang, Hairong.,Tang, Weichao.,Wang, Can.,Huang, Chao.,...&Ouyang, Xinping.(2017).Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents.BIORESOURCES,12,8755-8774.
MLA Guo, Haijun,et al."Furfural Hydrogenation over Amorphous Alloy Catalysts Prepared by Different Reducing Agents".BIORESOURCES 12(2017):8755-8774.
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