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Alternative TitleEffects of the preparation solvent on structure and catalytic properties of NiCoB amorphous alloy catalysts for hydrogenation of furfural
郭海军1,2,3,4,5; 唐伟超1,2,3,4; 张海荣1,2,3,4; 彭芬1,2,3,4; 王璨1,2,3,4; 黄前霖1,2,3,4,6; 熊莲1,2,3,4; 陈新德1,2,3,4; 欧阳新平5; 邱学青5
Source Publication燃料化学学报
Other AbstractA series of NiCoB amorphous alloy catalysts were prepared by chemical reduction method in different single and mixed solvent systems and their performance for liquid phase hydrogenation of furfural( FUR) was evaluated. The catalysts were also characterized by N2 adsorption-desorption,ICP,FE-SEM,HRTEM,XRD and XPS. The results showed that the surface tension,viscosity,polarity and solubility parameter of preparation solvent had important effects on the composition,morphology,structure and the catalytic properties of FUR hydrogenation of the NiCoB amorphous alloy catalyst. The NiCoB-MEG catalyst prepared by the mixed solvent of methanol/ethylene glycol( MEG,volume ratio of 1 ∶ 1) showed the optimum liquid phase hydrogenation performance of FUR to furfuryl alcohol( FA) with a FUR conversion of 96.4% and a FA selectivity of 83.49%.It can be due to the improvement of dispersion and reduction of metallic components by the synergistic effect between methanol and ethylene glycol.
Keyword糠醛加氢 制备溶剂 NiCoB 非晶态合金催化剂 糠醇 hydrogenation of furfural preparation solvent NiCoB amorphous alloy catalysts furfuryl alcohol
Document Type期刊论文
Corresponding Author陈新德
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
郭海军,唐伟超,张海荣,等. 制备溶剂对NiCoB非晶态合金催化剂结构及糠醛加氢性能的影响[J]. 燃料化学学报,2017,45(7):817-827.
APA 郭海军.,唐伟超.,张海荣.,彭芬.,王璨.,...&邱学青.(2017).制备溶剂对NiCoB非晶态合金催化剂结构及糠醛加氢性能的影响.燃料化学学报,45(7),817-827.
MLA 郭海军,et al."制备溶剂对NiCoB非晶态合金催化剂结构及糠醛加氢性能的影响".燃料化学学报 45.7(2017):817-827.
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