GIEC OpenIR  > 中国科学院广州能源研究所
Alternative TitleChemical isomerization of glucose into fructose
张雄1; 徐志祥1; 李雪辉1; 关建郁1; 龙金星1,2
Source Publication化工进展
Other AbstractBiomass is the unique carbon-containing renewable material on the globe.It has long been considered as the most promising alternative for the fossil fuel in the production of versatile biochemical,such as 5-hydromethylfurfuran and levulinic acid.It should be noted that the isomerization of glucose to fructose is the most crucial process in above mentioned bio-refining.Furthermore,the isomerization of glucose is very important in the food science as well.Therefore,it has been widely investigated.In this paper,an overview on the recent achievement and progress on the chemocatalytic isomerization of glucose to fructose was presented.Both conventional acid-base catalysts(such as Br?nsted base,solid base,metal salt and molecular sieve) and novel catalyst materials(for example,metal organic frameworks and ionic liquids) were intensively summarized.The acid and alkali catalytic mechanism for glucose isomerization were briefly introduced,and the current research methods were summarized as well.The key technical barriers on current glucose isomerization processes were discussed,such as poor catalyst stability,low process efficiency and low fructose selectivity.In additional,the probable strategies,for example,the design of water-resistant catalysts and the construction of coupling process for glucose catalytic isomerization and the in situ fructose separation,were propsed.The development of efficient and novel catalysts and catalytic systems,green chemical process for the promoted glucose isomerization performance,and the application of modern analysis methods(such as in situ technique,2D-nuclear magnetic resonance and computational simulation)on the catalytic mechanism investigation will be drawn more attentions in the future research on efficient glucose isomerization.
Keyword葡萄糖 果糖 异构 催化剂 glucose fructose isomerization catalysis
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Document Type期刊论文
Corresponding Author龙金星
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GB/T 7714
张雄,徐志祥,李雪辉,等. 葡萄糖化学催化异构制备果糖研究进展[J]. 化工进展,2017,36(12):4575-4585.
APA 张雄,徐志祥,李雪辉,关建郁,&龙金星.(2017).葡萄糖化学催化异构制备果糖研究进展.化工进展,36(12),4575-4585.
MLA 张雄,et al."葡萄糖化学催化异构制备果糖研究进展".化工进展 36.12(2017):4575-4585.
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