Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子 | |
Alternative Title | Modeling study on the biomass char gasification kinetics under CO2 atmosphere:Ⅱ. Pre-exponential factor |
汪小憨1,2![]() ![]() | |
2017-05 | |
Source Publication | 燃料化学学报
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ISSN | 0253-2409 |
Volume | 45Issue:5Pages:529-536 |
Abstract | 基于简单碰撞理论,建立了生物质焦炭CO2气化反应速率的计算方法,找出了表征指数前因子大小的关键组合参数。在此基础上,对六种生物质及其脱灰焦炭的物理化学特性进行了检测分析,利用热重分析仪在800-1 000℃对各种生物质进行了CO2等温气化实验,将得到的指数前因子实验数据与模型分析结果进行对比。研究表明,指数前因子与构建的组合参数之间存在较好的相关性,建立的通用关系式可为气化反应规律的进一步阐明提供有益的参考。 |
Other Abstract | Based on the simple collision theory(SCT),the calculation method of biomass char gasification rate was developed and the combined parameters to characterize the pre-exponential factor were found. Furthermore,some experimental tests for six acid-washed biomass chars,such as the isothermal gasification and so on,were performed under CO2 atmosphere,using a thermo-gravimetric analyzer(TGA) over the temperature ranges of 800-1 000 ℃,respectively. Through the comparison of experimental data and modeling results,it is found that a good agreement is made and the developed model equations can provide an effective guidance to clarify the general gasification law of biomass chars. |
Keyword | 生物质焦炭 CO2气化 简单碰撞理论 指数前因子 模型研究 biomass char CO2 gasification simple collision theory pre-exponential factor modelling |
Language | 中文 |
CSCD ID | CSCD:5991650 |
Document Type | 期刊论文 |
Identifier | http://ir.giec.ac.cn/handle/344007/16520 |
Collection | 中国科学院广州能源研究所 |
Corresponding Author | 汪小憨 |
Affiliation | 1.中国科学院广州能源研究所,广东广州510640; 2.中国科学院可再生能源重点实验室,广东广州510640; 3.中国科学院大学,北京100049 |
First Author Affilication | GuangZhou Institute of Energy Conversion,Chinese Academy of Sciences |
Recommended Citation GB/T 7714 | 汪小憨,宋谦石,曾小军,等. CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子[J]. 燃料化学学报,2017,45(5):529-536. |
APA | 汪小憨,宋谦石,曾小军,&吴勇.(2017).CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子.燃料化学学报,45(5),529-536. |
MLA | 汪小憨,et al."CO2气氛下生物质焦气化反应动力学模型研究:Ⅱ.指数前因子".燃料化学学报 45.5(2017):529-536. |
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