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Quantitative investigation on the characteristics of ions transport into water in gas shale: Marine and continental shale as comparative study
Yang, Liu1,2,3; Shi, Xian4; Ge, Hongkui2; Liu, Dunqing2; Qu, Xiangmei2; Gao, Jian5; Li, Lingdong5; Xu, Peng5; Tan, Xiqun5
2017-10-01
发表期刊JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING
ISSN1875-5100
卷号46页码:251-264
摘要Investigating ions transport from matrix pores to water is essential for understanding the salinity profiles of shale gas. Previous publications have shown that salt ions can be sourced from the dissolution of precipitated salts and leaching of clay minerals. However, neither a clear standard method nor generally accepted evaluation parameters have been proposed for a quantitative study of the impact and role of these two factors. In this work, a new method based on crushed samples is proposed to avoid the influence of microfractures, and simulate the ions advection and diffusion into water. The characteristic parameters and influencing factors are studied by conducting comparative experiments on sandstone, marine and continental shale samples. The preliminary results showed that it is a credible method to study the impact of precipitated salts and clay minerals. Each transport curve can be divided into three parts: a linear imbibition-diffusion part, non-linear transition part and diffusion part. Three parameters of surface ions density, ions diffusion rate and ions transport capacity can be used for quantitative characterization. Compared with sandstone of relatively higher permeability, shale has a much larger surface ion density and ions diffusion rate, resulting in stronger ions transport capacity. Marine shale has a larger surface ions density than continental shale, suggesting that SID is primarily determined by precipitated salts. However, continental shale has a larger ions diffusion rate than marine shale, leading to a stronger ion transport capacity. It can be explained by more clay minerals in continental shale. Clay minerals that correspond to higher cation exchange capacity and specific surface area can promote faster ion exchange reactions. By comparison with dissolution of precipitated salts, leaching of clay minerals is the dominant mechanism for ion transfer from shale to water. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Article
关键词Shale Imbibition Ions Diffusion Fracturing
WOS标题词Science & Technology ; Technology
DOI10.1016/j.jngse.2017.07.020
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]IMBIBITION ; ADSORPTION ; FRACTURES
收录类别SCI
语种英语
项目资助者Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; 2016M601141) ; 2016M601141) ; 2016M601141) ; 2016M601141) ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Key Laboratory of Gas Hydrate, Guangzhou Institute of Energy Conversion - Postdoctoral Science Foundation(Y707kj1001 ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; Foundation of Shale Oil and Gas Enrichment Mechanisms and Effective Development(G5800-15-ZS-WX047) ; 2016M601141) ; 2016M601141) ; 2016M601141) ; 2016M601141)
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000413607200020
出版者ELSEVIER SCI LTD
引用统计
被引频次:10[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/16495
专题中国科学院广州能源研究所
通讯作者Yang, Liu; Shi, Xian
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China
2.China Univ Petr, State Key Lab Petr Resources & Prospecting, Beijing 102249, Peoples R China
3.Chinese Acad Sci, Inst Mech, Key Lab Mech Fluid Solid Coupling Syst, Beijing 100190, Peoples R China
4.China Univ Petr East China, Sch Petr Engn, Qingdao 266580, Peoples R China
5.Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China
第一作者单位中国科学院广州能源研究所
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GB/T 7714
Yang, Liu,Shi, Xian,Ge, Hongkui,et al. Quantitative investigation on the characteristics of ions transport into water in gas shale: Marine and continental shale as comparative study[J]. JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING,2017,46:251-264.
APA Yang, Liu.,Shi, Xian.,Ge, Hongkui.,Liu, Dunqing.,Qu, Xiangmei.,...&Tan, Xiqun.(2017).Quantitative investigation on the characteristics of ions transport into water in gas shale: Marine and continental shale as comparative study.JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING,46,251-264.
MLA Yang, Liu,et al."Quantitative investigation on the characteristics of ions transport into water in gas shale: Marine and continental shale as comparative study".JOURNAL OF NATURAL GAS SCIENCE AND ENGINEERING 46(2017):251-264.
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