Py-GC/MS study of lignin pyrolysis and effect of catalysts on product distribution

doi:10.25165/j.ijabe.20171005.2852

GIEC OpenIR > 生物质化工品制备实验室

	Py-GC/MS study of lignin pyrolysis and effect of catalysts on product distribution
	Si Zhan 1,2,3; Wang Chenguang 2; Bi Kang 2,4; Zhang Xinghua2 ; Yu Chiling 5; Dong Renjie 1,3,6; Ma Longlong2 ; Pang Changle 7
	2017-09-01
发表期刊	INTERNATIONAL JOURNAL OF AGRICULTURAL AND BIOLOGICAL ENGINEERING
ISSN	1934-6344
卷号	10 期号:5 页码:214-225
摘要	Fast pyrolysis is one of the most promising methods to convert lignin into fuels and chemicals. In the present study, pyrolysis-gas chromatography/mass spectrometry (Py-GC/MS) was used to evaluate vapor phase product distribution of lignin fast pyrolysis. During the non-catalytic pyrolysis process, lignin was pyrolyzed at 400 degrees C, 500 degrees C and 600 degrees C respectively, finding that the highest yield of aromatic hydrocarbons was obtained at 600 degrees C. Catalytic pyrolysis experiments were also conducted to investigate the effects of catalyst pore structure and acidity on the product distributions. Five different catalysts (HZSM-5, MCM-41, TiO2, ZrO2 and Mg(Al) O) were applied to lignin catalytic pyrolysis, and the catalytic performance was estimated by analyzing the pyrolytic products. The catalysts were characterized by using X-ray diffraction ( XRD), BET, and NH3 (CO2) temperature programmed desorption. Based on these characterizations, discussion was carried out to explain the formation of the produc distributions. Among the five catalysts, HZSM-5 exhibited the best performance on the formation of aromatic hydrocarbons.
文章类型	Article
关键词	Lignin Py-gc/ms Fast Pyrolysis Catalytic Upgrading Pore Structure Acid-base Property
WOS标题词	Science & Technology ; Life Sciences & Biomedicine
DOI	10.25165/j.ijabe.20171005.2852
研究领域[WOS]	Agriculture
关键词[WOS]	FLUIDIZED-BED REACTOR ; BIOMASS PYROLYSIS ; SHAPE SELECTIVITY ; KRAFT LIGNIN ; FUELS ; CHEMICALS ; ZEOLITE ; HYDROCARBONS ; CONVERSION ; ACIDITY
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation of China(51536009) ; National Natural Science Foundation of China(51536009) ; NSFC (Natural Science Foundation of China) project(51476175) ; NSFC (Natural Science Foundation of China) project(51476175) ; National Basic Research Program of China(2013CB228105) ; National Basic Research Program of China(2013CB228105) ; Chinese Academy of Sciences "one hundred talented plan" ; Chinese Academy of Sciences "one hundred talented plan" ; Beijing Municipal Key Discipline of Biomass Engineering ; Beijing Municipal Key Discipline of Biomass Engineering ; National Natural Science Foundation of China(51536009) ; National Natural Science Foundation of China(51536009) ; NSFC (Natural Science Foundation of China) project(51476175) ; NSFC (Natural Science Foundation of China) project(51476175) ; National Basic Research Program of China(2013CB228105) ; National Basic Research Program of China(2013CB228105) ; Chinese Academy of Sciences "one hundred talented plan" ; Chinese Academy of Sciences "one hundred talented plan" ; Beijing Municipal Key Discipline of Biomass Engineering ; Beijing Municipal Key Discipline of Biomass Engineering
WOS类目	Agricultural Engineering
WOS记录号	WOS:000412990100021
出版者	CHINESE ACAD AGRICULTURAL ENGINEERING
引用统计	被引频次：10[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/16388
专题	生物质化工品制备实验室生物质能源
通讯作者	Wang Chenguang; Dong Renjie
作者单位	1.China Agr Univ, Coll Engn, Bioenergy & Environm Sci & Technol Lab, Beijing 100083, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China 3.Minist Agr, Key Lab Clean Prod & Utilizat Renewable Energy, Beijing 100083, Peoples R China 4.Zhengzhou Univ, Sch Chem Engn & Energy, Zhengzhou 450001, Henan, Peoples R China 5.Chinese Acad Sci, Guangzhou Inst Geochem, State Key Lab Organ Geochem, Guangzhou 510640, Guangdong, Peoples R China 6.Minist Sci & Technol, Natl Ctr Int Res BioEnergy Sci & Technol, Beijing 100083, Peoples R China 7.China Agr Univ, Dept Vehicle Engn, Coll Engn, Beijing 100083, Peoples R China
推荐引用方式 GB/T 7714	Si Zhan,Wang Chenguang,Bi Kang,et al. Py-GC/MS study of lignin pyrolysis and effect of catalysts on product distribution[J]. INTERNATIONAL JOURNAL OF AGRICULTURAL AND BIOLOGICAL ENGINEERING,2017,10(5):214-225.
APA	Si Zhan.,Wang Chenguang.,Bi Kang.,Zhang Xinghua.,Yu Chiling.,...&Pang Changle.(2017).Py-GC/MS study of lignin pyrolysis and effect of catalysts on product distribution.INTERNATIONAL JOURNAL OF AGRICULTURAL AND BIOLOGICAL ENGINEERING,10(5),214-225.
MLA	Si Zhan,et al."Py-GC/MS study of lignin pyrolysis and effect of catalysts on product distribution".INTERNATIONAL JOURNAL OF AGRICULTURAL AND BIOLOGICAL ENGINEERING 10.5(2017):214-225.