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Characterization and performance of Cu( In, Ga)Se-2 thin films incorporating low-temperature pre-annealing process
Zhang, Xiaoqing1,2; Huang, Yunxiang1; Yuan, Wei1; Tang, Yong1
2017-12-25
发表期刊JOURNAL OF ALLOYS AND COMPOUNDS
ISSN0925-8388
卷号728页码:29-36
摘要This paper focuses on the characterization and performance evaluation of the Cu(In, Ga)Se-2 (CIGS) thin films fabricated using the low-temperature pre-annealing process, followed by the plasma-enhanced Se vapor selenization coupled with etching (PESVSE) and thermal-assisted Se vapor selenization (TASVS). The XPS data reveals that the increase of pre-annealing temperature can facilitate the diffusion of Ga towards the surface of CIGS thin film by stabilizing more Ga distribution on the surface of the annealed precursor. The PESVSE process can effectively increase Ga content on the film surface with the help of low-temperature pre-annealing process. Results also indicate that the PESVSE combined with a low-temperature pre-annealing process can significantly weaken and even eliminate the adverse phase separation to yield a single-phase CIGS thin film with a moderate Ga content. The PESVSE process helps to improve and even achieve a homogeneous depth distribution of Ga in the whole CIGS thin film in comparison with the TASVS process. The PESVSE process achieves a higher open circuit voltage and also higher conversion efficiency of CIGS solar cell treated by the low-temperature pre-annealing process. The feasibility of using this low-temperature pre-annealing method to make high-quality CIGS thin films for photovoltaic applications has been successfully validated in this work. (C) 2017 Elsevier B.V. All rights reserved.
文章类型Article
关键词Cigs Solar Cell Low-temperature Pre-annealing Plasma-enhanced Selenization Thin Film
WOS标题词Science & Technology ; Physical Sciences ; Technology
DOI10.1016/j.jallcom.2017.08.259
研究领域[WOS]Chemistry ; Materials Science ; Metallurgy & Metallurgical Engineering
关键词[WOS]CU(IN,GA)SE-2 SOLAR-CELLS ; SELENIZATION PROCESS ; SE VAPOR ; BARRIER LAYER ; PRECURSORS ; EFFICIENCY ; DIFFUSION ; MOSE2 ; PANEL
收录类别SCI
语种英语
项目资助者National Natural Science Foundation of China(51475172) ; National Natural Science Foundation of China(51475172) ; Natural Science Foundation of Guangdong Province(2015A030306013 ; Natural Science Foundation of Guangdong Province(2015A030306013 ; key program of NSFC-Guangdong Joint Funds of China(U1401249) ; key program of NSFC-Guangdong Joint Funds of China(U1401249) ; 2014A030312017) ; 2014A030312017) ; National Natural Science Foundation of China(51475172) ; National Natural Science Foundation of China(51475172) ; Natural Science Foundation of Guangdong Province(2015A030306013 ; Natural Science Foundation of Guangdong Province(2015A030306013 ; key program of NSFC-Guangdong Joint Funds of China(U1401249) ; key program of NSFC-Guangdong Joint Funds of China(U1401249) ; 2014A030312017) ; 2014A030312017)
WOS类目Chemistry, Physical ; Materials Science, Multidisciplinary ; Metallurgy & Metallurgical Engineering
WOS记录号WOS:000412818600004
出版者ELSEVIER SCIENCE SA
引用统计
被引频次:3[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/16386
专题中国科学院广州能源研究所
通讯作者Yuan, Wei
作者单位1.South China Univ Technol, Sch Mech & Automot Engn, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
第一作者单位中国科学院广州能源研究所
推荐引用方式
GB/T 7714
Zhang, Xiaoqing,Huang, Yunxiang,Yuan, Wei,et al. Characterization and performance of Cu( In, Ga)Se-2 thin films incorporating low-temperature pre-annealing process[J]. JOURNAL OF ALLOYS AND COMPOUNDS,2017,728:29-36.
APA Zhang, Xiaoqing,Huang, Yunxiang,Yuan, Wei,&Tang, Yong.(2017).Characterization and performance of Cu( In, Ga)Se-2 thin films incorporating low-temperature pre-annealing process.JOURNAL OF ALLOYS AND COMPOUNDS,728,29-36.
MLA Zhang, Xiaoqing,et al."Characterization and performance of Cu( In, Ga)Se-2 thin films incorporating low-temperature pre-annealing process".JOURNAL OF ALLOYS AND COMPOUNDS 728(2017):29-36.
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