GIEC OpenIR  > 中国科学院广州能源研究所
Insight into forced hydrogen re-arrangement and altered reaction pathways in a protocol for CO2 catalytic processing of oleic acid into C-8-C-15 alkanes
Xing, Shiyou1,2,3,4; Lv, Pengmei1,2,4,5; Yuan, Haoran1,2,4; Yang, Lingmei1,2,4; Wang, Zhongming1,2,4,5; Yuan, Zhenhong1,2,4,5; Chen, Yong1,2,4
2017-09-07
发表期刊GREEN CHEMISTRY
卷号19期号:17页码:4157-4168
摘要A new vision of using carbon dioxide (CO2) catalytic processing of oleic acid into C-8-C-15 alkanes over a nano-nickel/zeolite catalyst is reported in this paper. The inherent and essential reasons which make this achievable are clearly resolved by using totally new catalytic reaction pathways of oleic acid transformation in a CO2 atmosphere. The yield of C-8-C-15 ingredients reaches 73.10 mol% in a CO2 atmosphere, which is much higher than the 49.67 mol% yield obtained in a hydrogen (H-2) atmosphere. In the absence of an external H-2 source, products which are similar to aviation fuel are generated where aromatization of propene (C3H6) oxidative dehydrogenation (ODH) involving CO2 and propane (C3H8) and hydrogen transfer reactions are found to account for hydrogen liberation in oleic acid and achieve its re-arrangement in the final alkane products. The reaction pathway in the CO2 atmosphere is significantly different from that in the H-2 atmosphere, as shown by the presence of 8-heptadecene, gamma-stearolactone, and 3-heptadecene as reaction intermediates, as well as a CO formation pathway. Because of the highly dispersed Ni metal center on the zeolite support, H-2 spillover is observed in the H-2 atmosphere, which inhibits the production of short-chain alkanes and reveals the inherent disadvantage of using H-2. The CO2 processing of oleic acid described in this paper will significantly contribute to future CO2 utilization chemistry and provide an economical and promising approach for the production of sustainable alkane products which are similar to aviation fuel.
文章类型Article
WOS标题词Science & Technology ; Physical Sciences
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2015A030313720 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2016A030308004) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2015A030313720 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2016A030308004)
DOI10.1039/c7gc01853c
研究领域[WOS]Chemistry
关键词[WOS]FATTY-ACID ; CRACKING CATALYSTS ; STEARIC-ACID ; FORMIC-ACID ; N-PENTANE ; CARBON-DIOXIDE ; DEOXYGENATION ; HYDROCARBONS ; CONVERSION ; SPILLOVER
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2015A030313720 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2016A030308004) ; National Natural Science Foundation of China(21576260) ; Natural Science Foundation of Guangdong Province(2015A030313720 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 2016A030308004)
WOS类目Chemistry, Multidisciplinary
WOS记录号WOS:000408588100023
引用统计
被引频次:1[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/16296
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
5.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
推荐引用方式
GB/T 7714
Xing, Shiyou,Lv, Pengmei,Yuan, Haoran,et al. Insight into forced hydrogen re-arrangement and altered reaction pathways in a protocol for CO2 catalytic processing of oleic acid into C-8-C-15 alkanes[J]. GREEN CHEMISTRY,2017,19(17):4157-4168.
APA Xing, Shiyou.,Lv, Pengmei.,Yuan, Haoran.,Yang, Lingmei.,Wang, Zhongming.,...&Chen, Yong.(2017).Insight into forced hydrogen re-arrangement and altered reaction pathways in a protocol for CO2 catalytic processing of oleic acid into C-8-C-15 alkanes.GREEN CHEMISTRY,19(17),4157-4168.
MLA Xing, Shiyou,et al."Insight into forced hydrogen re-arrangement and altered reaction pathways in a protocol for CO2 catalytic processing of oleic acid into C-8-C-15 alkanes".GREEN CHEMISTRY 19.17(2017):4157-4168.
条目包含的文件
条目无相关文件。
个性服务
推荐该条目
保存到收藏夹
查看访问统计
导出为Endnote文件
谷歌学术
谷歌学术中相似的文章
[Xing, Shiyou]的文章
[Lv, Pengmei]的文章
[Yuan, Haoran]的文章
百度学术
百度学术中相似的文章
[Xing, Shiyou]的文章
[Lv, Pengmei]的文章
[Yuan, Haoran]的文章
必应学术
必应学术中相似的文章
[Xing, Shiyou]的文章
[Lv, Pengmei]的文章
[Yuan, Haoran]的文章
相关权益政策
暂无数据
收藏/分享
所有评论 (0)
暂无评论
 

除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。