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橄榄石对甲苯催化重整反应的影响
Alternative TitleEffects of olivine on catalytic reforming of toluene
李兰兰1,2; 郑安庆1; 冯宜鹏1,2; 孟俊光1,2; 赵增立1; 李海滨1
2015
Source Publication燃料化学学报
Issue7Pages:806-815
AbstractWith toluene as the model compound of tar from biomass gasification, the catalytic properties of olivine and nickel catalysts supported on the olivine were analyzed for its performance on the reactions of toluene cracking and toluene/steam reforming in a
Other Abstract在固定床反应器上,以甲苯为生物质气化焦油的模型化合物,对橄榄石以及其负载镍催化剂对甲苯裂解反应和甲苯/水蒸气重整反应的催化性能进行了研究,并对催化剂进行了SEM、BET、XRD、H2-TPR等表征。结果表明,煅烧使原矿的物化特性发生改变,橄榄石对甲苯裂解反应和重整反应有一定的催化活性。而Ni的引入,使催化剂对甲苯裂解反应的活性有所降低,甲苯的转化率降低2.2%~9.8%;但催化剂对甲苯/水蒸气重整反应的活性升高,甲苯的转化率可高达97.0%,并且载镍橄榄石催化剂对甲苯/水蒸气重整反应有较强的稳定性。
Keyword橄榄石 镍催化剂 甲苯 催化重整
Funding Organization国家自然科学基金项目(51376186,21406227);广东省科技划项目(20128050500007).
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/16173
Collection中国科学院广州能源研究所
Affiliation1.中国科学院广州能源研究所中国科学院可再生能源重点实验室,广东广州510640
2.中国科学院大学,北京100049
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
李兰兰,郑安庆,冯宜鹏,等. 橄榄石对甲苯催化重整反应的影响[J]. 燃料化学学报,2015(7):806-815.
APA 李兰兰,郑安庆,冯宜鹏,孟俊光,赵增立,&李海滨.(2015).橄榄石对甲苯催化重整反应的影响.燃料化学学报(7),806-815.
MLA 李兰兰,et al."橄榄石对甲苯催化重整反应的影响".燃料化学学报 .7(2015):806-815.
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