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基于等转化率法的生物焦CO-2气化反应动力学参数研究
Alternative TitleStudy on gasification kinetic parameter of biomass char based on iso-conversional method under CO_2 atmosphere
邵振华1,2; 汪小憨1; 曾小军1
2015
Source Publication可再生能源
Issue4Pages:598-603
AbstractThe isothermal gasification tests of rice straw char and wood chip char were carried out under CO2 atmosphere,using the thermo-gravimetric analyzer(TGA) over the temperature range of 800~950 ℃. The gasification reactivity of two chars increased with the i
Other Abstract利用热重分析仪在800-950℃对稻秆焦和木屑焦CO2等温气化过程进行了研究。分别采用等转化率法和随机孔模型求解了稻秆焦和木屑焦气化反应的动力学参数。通过等转化率法发现,随着碳转化率的增加,反应活化能随着碳转化率的升高而增大,稻秆焦和木屑焦在碳转化率为0.02时刻(即接近初始时刻)的活化能分别为157.2 k J/mol和166.4 k J/mol;采用随机孔模型计算得到稻秆焦和木屑焦的活化能分别为155.1 k J/mol和165.5 k J/mol,与等转化率法求得的碳转化率为0.02时刻的活化能接近
KeywordCo2气化 等转化率法 随机孔模型 结构参数
Funding Organization国家自然科学基金(51276184); 国家重点基础研究发展计划(2011CB201501)
Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/16159
Collection中国科学院广州能源研究所
Affiliation1.中国科学院广州能源研究所,广东广州510640
2.中国科学院大学,北京100049
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
邵振华,汪小憨,曾小军. 基于等转化率法的生物焦CO-2气化反应动力学参数研究[J]. 可再生能源,2015(4):598-603.
APA 邵振华,汪小憨,&曾小军.(2015).基于等转化率法的生物焦CO-2气化反应动力学参数研究.可再生能源(4),598-603.
MLA 邵振华,et al."基于等转化率法的生物焦CO-2气化反应动力学参数研究".可再生能源 .4(2015):598-603.
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