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Alternative TitleHydrodeoxygenation of Anisole over Ni/α-Al2O3 Catalyst
汤文武1,3; 张兴华2,3; 张琦2,3; 王铁军2,3; 马隆龙2,3
Source Publication化学物理学报
Cooperation Status国内
AbstractNi-based catalysts supported on di erent supports (α-Al2O3,γ-Al2O3, SiO2, TiO2, and ZrO2) were prepared by impregnation. Effects of supports on catalytic performance were tested using hydrodeoxygenation reaction (HDO) of anisole as model reaction. Ni/α-Al
Other Abstract通过化学沉淀法制备了以α-Al2O3、γ-Al2O3、SiO2,TiO2和ZrO2为载体的五种镍基催化剂,以苯甲醚为模型化合物对催化剂进行活性评价,考察载体对加氢脱氧催化反应的影响。实验表明,Ni/α-Al2O3对苯甲醚加氢脱氧反应的催化活性最高。在优化的工况下,苯甲醚的转化率达到93.25%,碳氢化合物收率达到90.47%。H2-TPD测试表明五种镍基催化剂中,Ni/α-Al2O3表面拥有更多的活性金属位,具有更高的加氢催化活性。Ni/α-Al2O3催化剂具有优异的可重复使用性能,反应后催化剂表面的积碳
Keyword苯甲醚 加氢脱氧 Ni/α-al2o3 碳氢化合物
Indexed BySCI
Document Type期刊论文
2.中国科学院可再生能源重点实验室,广州 510640
3.中国科学院广州能源研究所,广州 510640
First Author AffilicationGuangZhou Institute of Energy Conversion,Chinese Academy of Sciences
Recommended Citation
GB/T 7714
汤文武,张兴华,张琦,等. Ni/α-Al2O3催化剂作用下苯甲醚的加氢脱氧[J]. 化学物理学报,2016(5):617-622.
APA 汤文武,张兴华,张琦,王铁军,&马隆龙.(2016).Ni/α-Al2O3催化剂作用下苯甲醚的加氢脱氧.化学物理学报(5),617-622.
MLA 汤文武,et al."Ni/α-Al2O3催化剂作用下苯甲醚的加氢脱氧".化学物理学报 .5(2016):617-622.
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