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电化学沉积制备V2O5薄膜电极的表面结构及储钠性能
Alternative TitleSurface morphology and sodium storage performance of V2O5 thin film electrode prepared by CTAB assisted electrodeposition
李延伟1,2; 李世玉1; 谢志平1; 姚金环1; 姜吉琼1; 张灵志2
2016
Source Publication化工学报
Issue11Pages:4771-4778
Cooperation Status国内
AbstractNew V2O5 nanofilm electrodes without binder and conductive agents were fabricated by sintering the V2O5 film precursor at 300℃ on stainless steel substrates, which were coated from CTAB-containing V2O5 sol gel electrolyte by electrodeposition. X-Ray diffr
Subtype期刊
Other Abstract以含有CTAB的V2O5溶胶为电解液,采用电沉积法在不锈钢基体上沉积V2O5薄膜前体,经300℃烧结处理后制备了无黏结剂和导电剂的V2O5纳米薄膜电极。XRD测试表明该方法制备的V2O5薄膜是含水相的V2O5·n H2O,与未添加CTAB制备的薄膜相比,其层间距明显变大。FESEM和AFM测试发现CTAB辅助电沉积制备的V2O5薄膜具有粗糙多孔的表面形貌;XPS测试表明CTAB辅助电沉积制备的V2O5薄膜中含有更多的低价钒离子(V4+)。电化学测试发现该方法制备的V2O5薄膜具有优异的嵌/脱Na
Keyword钠离子电池 正极材料 制备 电化学 纳米材料
Indexed ByCSCD ; SCI
Language中文
Funding Organization国家自然科学基金项目(21263003,51664012,51464009);广西自然科学基金项目(2015GXNSFGA139006,2014GXNSFBA118238);中国科学院可再生能源重点实验室项目(y507k61001)
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Document Type期刊论文
Identifierhttp://ir.giec.ac.cn/handle/344007/15940
Collection中国科学院广州能源研究所
Affiliation1.广西电磁化学功能物质重点实验室,桂林理工大学化学与生物工程学院,广西桂林541004
2.中国科学院可再生能源重点实验室,广东广州 510640
Recommended Citation
GB/T 7714
李延伟,李世玉,谢志平,等. 电化学沉积制备V2O5薄膜电极的表面结构及储钠性能[J]. 化工学报,2016(11):4771-4778.
APA 李延伟,李世玉,谢志平,姚金环,姜吉琼,&张灵志.(2016).电化学沉积制备V2O5薄膜电极的表面结构及储钠性能.化工学报(11),4771-4778.
MLA 李延伟,et al."电化学沉积制备V2O5薄膜电极的表面结构及储钠性能".化工学报 .11(2016):4771-4778.
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