GLUCOSE-DERIVED CARBONACEOUS SOLID ACID CATALYST FOR CELLOOLIGOSACCHARIDES HYDROLYSIS IN AN AQUEOUS REACTION SYSTEM

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	GLUCOSE-DERIVED CARBONACEOUS SOLID ACID CATALYST FOR CELLOOLIGOSACCHARIDES HYDROLYSIS IN AN AQUEOUS REACTION SYSTEM
	Liu, Wan-Yu 1; Qi, Wei 2; Liu, Shu-Na 2; Wang, Qiong 2; Zhou, Jin-Song 1; Yuan, Zhen-Hong 2; Zhuang, Xin-Shu 2
	2017-05-01
发表期刊	CELLULOSE CHEMISTRY AND TECHNOLOGY
卷号	51 期号:5-6 页码:417-423
摘要	An amorphous carbon based catalyst was prepared by carbonation and sulfonation of several typical biomass materials, including glucose, microcrystalline cellulose, sugarcane bagasse, eucalyptus, switchgrass and microalgae. Preliminary experimental results on cellobiose hydrolysis indicated that the catalyst prepared from glucose exhibited the highest catalytic activity. Thus, methods, including SEM, XRD, FT-IR, NH3-TPD and elemental analysis, were employed to characterize the catalyst before and after sulfonation. Compared with other conventional solid acid catalysts, the catalyst bearing -SO3H, -COOH, and -OH groups exhibited remarkable activity in the hydrolysis of beta-1,4-glycosidic bonds and no other by-reactions were detected in further hydrolysis experiments. After the hydrolysis reaction, the solid acid catalyst could be readily separated from the saccharide solution for reuse without any significant loss of activity.
文章类型	Article
关键词	Carbonaceous Solid Acid Hydrolysis Cellooligosaccharides
WOS标题词	Science & Technology ; Technology
研究领域[WOS]	Materials Science
关键词[WOS]	IONIC LIQUID ; AMORPHOUS-CARBON ; CELLULOSE ; PRETREATMENT ; BAGASSE ; WATER
收录类别	SCI
语种	英语
项目资助者	National Natural Science Foundation(21376241 ; 51506207 ; 51561145015 ; 51206173)
WOS类目	Materials Science, Paper & Wood
WOS记录号	WOS:000413719200004
引用统计	被引频次：3[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/15863
专题	中国科学院广州能源研究所
作者单位	1.Zhejiang Univ, State Key Lab Clean Energy Utilizat, Hangzhou 310027, Zhejiang, Peoples R China 2.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Liu, Wan-Yu,Qi, Wei,Liu, Shu-Na,et al. GLUCOSE-DERIVED CARBONACEOUS SOLID ACID CATALYST FOR CELLOOLIGOSACCHARIDES HYDROLYSIS IN AN AQUEOUS REACTION SYSTEM[J]. CELLULOSE CHEMISTRY AND TECHNOLOGY,2017,51(5-6):417-423.
APA	Liu, Wan-Yu.,Qi, Wei.,Liu, Shu-Na.,Wang, Qiong.,Zhou, Jin-Song.,...&Zhuang, Xin-Shu.(2017).GLUCOSE-DERIVED CARBONACEOUS SOLID ACID CATALYST FOR CELLOOLIGOSACCHARIDES HYDROLYSIS IN AN AQUEOUS REACTION SYSTEM.CELLULOSE CHEMISTRY AND TECHNOLOGY,51(5-6),417-423.
MLA	Liu, Wan-Yu,et al."GLUCOSE-DERIVED CARBONACEOUS SOLID ACID CATALYST FOR CELLOOLIGOSACCHARIDES HYDROLYSIS IN AN AQUEOUS REACTION SYSTEM".CELLULOSE CHEMISTRY AND TECHNOLOGY 51.5-6(2017):417-423.