Knowledge Management System Of Guangzhou Institute of Energy Conversion, CAS
Swapping methane with carbon dioxide in spherical hydrate pellets | |
Zhou, Xuebing1,2,3; Li, Dongliang1,2,3; Zhang, Shaohong1; Liang, Deqing1,2,3 | |
2017-12-01 | |
发表期刊 | ENERGY |
卷号 | 140页码:136-143 |
摘要 | Recovering CH4 with CO2 in hydrocarbon hydrates is renowned as an eco-friendly method for potential energy production and climate change mitigation. Due to the foamy nature of hydrates, determining the effect of hydrate surface area on the CH4 recovering rate has always been a challenge. CH4 hydrates in this work were shaped into spherical pellets 16 mm in diameter, and the CH4-CO2 replacements were carried out at about 274 K, 3.0 MPa by adding different amount of pellets in the reactor. To reveal the kinetic properties, cryo-SEM and a model based on gas diffusion theory was also employed. Results indicated that the CH4 recovery rate in the replacement was proportional to the surface area of hydrate pellets. In each 1400-h replacement, the CH4 production level was found to be about 4.5%, suggesting the gas swapping process tool< place in each pellet was the same. The kinetic model provided well descriptions of the replacements with the average deviation no more than 10%. The SEM images and the gas diffusion constants obtained from the kinetic model suggested that water mobility determined the gas diffusion rate in hydrates and help to smooth the hydrate surface during replacements. (C) 2017 Elsevier Ltd. All rights reserved. |
文章类型 | Article |
关键词 | Gas Hydrate Methane Carbon Dioxide Sem |
WOS标题词 | Science & Technology ; Physical Sciences ; Technology |
DOI | 10.1016/j.energy.2017.08.082 |
研究领域[WOS] | Thermodynamics ; Energy & Fuels |
关键词[WOS] | NATURAL-GAS HYDRATE ; LIQUID CO2 ; IN-SITU ; REPLACEMENT ; KINETICS ; CH4 ; RECOVERY ; MIXTURE ; PRODUCTIVITY ; SPECTROSCOPY |
收录类别 | SCI |
语种 | 英语 |
项目资助者 | National Natural Science Foundation of China(51376182) ; CAS Program(KGZD-EW-301) ; Scientific cooperative project by CNPC ; CAS(2015A-4813) |
WOS类目 | Thermodynamics ; Energy & Fuels |
WOS记录号 | WOS:000415394200016 |
引用统计 | |
文献类型 | 期刊论文 |
条目标识符 | http://ir.giec.ac.cn/handle/344007/15862 |
专题 | 中国科学院广州能源研究所 |
作者单位 | 1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Key Lab Gas Hydrate, Guangzhou 510640, Guangdong, Peoples R China 2.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China 3.Chinese Acad Sci, Guangzhou Ctr Gas Hydrate Res, Guangzhou 510640, Guangdong, Peoples R China |
第一作者单位 | 中国科学院广州能源研究所 |
推荐引用方式 GB/T 7714 | Zhou, Xuebing,Li, Dongliang,Zhang, Shaohong,et al. Swapping methane with carbon dioxide in spherical hydrate pellets[J]. ENERGY,2017,140:136-143. |
APA | Zhou, Xuebing,Li, Dongliang,Zhang, Shaohong,&Liang, Deqing.(2017).Swapping methane with carbon dioxide in spherical hydrate pellets.ENERGY,140,136-143. |
MLA | Zhou, Xuebing,et al."Swapping methane with carbon dioxide in spherical hydrate pellets".ENERGY 140(2017):136-143. |
条目包含的文件 | 条目无相关文件。 |
除非特别说明,本系统中所有内容都受版权保护,并保留所有权利。
修改评论