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Synthesis of Glycerol-Free Biodiesel with Dimethyl Carbonate over Sulfonated Imidazolium Ionic Liquid
Fan, Pei1,2,3,4; Wang, Jiayan1,5; Xing, Shiyou1,2,3,4; Yang, Lingmei1,2,4; Yang, Gaixiu1,2,4; Fu, Junying1,2,4; Miao, Changlin1,2,4; Lv, Pengmei1,2,4,6
2017-04-01
发表期刊ENERGY & FUELS
卷号31期号:4页码:4090-4095
摘要Ionic liquid is a green solvent and catalyst. A new approach of using dimethyl carbonate (DMC) catalyzed by sulfonated imidazolium ionic liquid (SIIL) producing glycerol-free biodiesel was developed. Together with the fatty acid methyl ester (FAME), the other two products fatty acid 1,3-dimethoxypropyl ester and 1,3-dimethoxypropan-2-ol were also generated, which could be used as an oxygenate additive without separation from biodiesel. The overall reaction pathway was resolved upon the product analysis, which could well explain the whole process and product distributions. In this paper, the effects of the molar ratio of DMC/rapeseed oil, catalyst dosage, reaction temperature, and reaction time were explored. The highest yield of FAME with the SIIL catalyst 1-propylsulfonate-3-methylimidazolium hydrogen sulfate ([PrSO3HMIM][HSO4]) reached 95.77% under optimum conditions.
文章类型Article
WOS标题词Science & Technology ; Technology
资助者National Natural Science Foundation of China(21576260 ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 21506217) ; 2015A030313720) ; National Natural Science Foundation of China(21576260 ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 21506217) ; 2015A030313720)
DOI10.1021/acs.energyfuels.7b00115
研究领域[WOS]Energy & Fuels ; Engineering
关键词[WOS]FUNCTIONALIZED IMIDAZOLIUM ; SOYBEAN OIL ; SOFT ACIDS ; PALM OIL ; TRANSESTERIFICATION ; LIPASE ; FUEL ; ESTERIFICATION ; METHYLATION ; CHEMISTRY
收录类别SCI
语种英语
资助者National Natural Science Foundation of China(21576260 ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 21506217) ; 2015A030313720) ; National Natural Science Foundation of China(21576260 ; Natural Science Foundation of Guangdong Province(2016A030308004 ; Special Funds of Applied Science and Technology Research of Guangdong Province(2015B020241002) ; 21506217) ; 2015A030313720)
WOS类目Energy & Fuels ; Engineering, Chemical
WOS记录号WOS:000400039800080
引用统计
被引频次:2[WOS]   [WOS记录]     [WOS相关记录]
文献类型期刊论文
条目标识符http://ir.giec.ac.cn/handle/344007/14175
专题中国科学院广州能源研究所
作者单位1.Chinese Acad Sci, Guangzhou Inst Energy Convers, Guangzhou 510640, Guangdong, Peoples R China
2.Chinese Acad Sci, Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
3.Univ Chinese Acad Sci, Beijing 100049, Peoples R China
4.Guangdong Key Lab New & Renewable Energy Res & De, Guangzhou 510640, Guangdong, Peoples R China
5.Univ Sci & Technol China, Nano Sci & Technol Inst, Suzhou 215123, Jiangsu, Peoples R China
6.Collaborat Innovat Ctr Biomass Energy, Zhengzhou 450002, Henan, Peoples R China
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Fan, Pei,Wang, Jiayan,Xing, Shiyou,et al. Synthesis of Glycerol-Free Biodiesel with Dimethyl Carbonate over Sulfonated Imidazolium Ionic Liquid[J]. ENERGY & FUELS,2017,31(4):4090-4095.
APA Fan, Pei.,Wang, Jiayan.,Xing, Shiyou.,Yang, Lingmei.,Yang, Gaixiu.,...&Lv, Pengmei.(2017).Synthesis of Glycerol-Free Biodiesel with Dimethyl Carbonate over Sulfonated Imidazolium Ionic Liquid.ENERGY & FUELS,31(4),4090-4095.
MLA Fan, Pei,et al."Synthesis of Glycerol-Free Biodiesel with Dimethyl Carbonate over Sulfonated Imidazolium Ionic Liquid".ENERGY & FUELS 31.4(2017):4090-4095.
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