Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone

doi:10.1039/c7ra03995f

GIEC OpenIR > 中国科学院广州能源研究所

	Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone
	Zhu, Yuanshuai 1; Li, Wenzhi 1; Lu, Yijuan 1; Zhang, Tingwei 1; Jameel, Hasan 2; Chang, Hou-min 2; Ma, Longlong3
	2017
发表期刊	RSC ADVANCES
卷号	7 期号:48 页码:29916-29924
摘要	A resorcinol-formaldehyde resin carbon (RFC) catalyst with a well-developed, ordered, mesoporous framework was prepared using a soft template method at room temperature. The carbon was sulfonated in water using sulfanilic acid under mild atmospheric conditions. The sulfonated RFC (S-RFC) was characterized by N-2 adsorption-desorption, elemental analysis, TEM, XPS, and FT-IR. It was determined that S-RFC is an efficient solid acid catalyst for furfural production from xylose and corn stover in gamma-valerolactone (GVL). The effects of reaction time, reaction temperature, catalyst loading, substrate dosage and water concentration were investigated. 80% furfural yield and 100% xylose conversion were obtained from xylose at 170 degrees C in 15 min with 0.5 g catalyst. Comparatively, 68.6% furfural yield was achieved from corn stover at 200 degrees C in 100 min when using 0.6 g catalyst. Since there was no discernable decrease in furfural yield after multiple conversions utilizing the same catalyst, the recyclability of the catalyst is considered good.
文章类型	Article
WOS标题词	Science & Technology ; Physical Sciences
DOI	10.1039/c7ra03995f
研究领域[WOS]	Chemistry
关键词[WOS]	MICROWAVE-ASSISTED DEHYDRATION ; ORDERED MESOPOROUS CARBON ; LIGNOCELLULOSIC BIOMASS ; AQUEOUS-PHASE ; BIPHASIC SYSTEM ; LEVULINIC ACID ; CONVERSION ; LIQUID ; CHEMICALS ; HYDROGENATION
收录类别	SCI
语种	英语
项目资助者	State Key Program of National Natural Science Foundation of China(51536009) ; National Key Technology R&D Program of China(2015BAD15B06) ; international technology cooperation plan of Anhui(1503062030)
WOS类目	Chemistry, Multidisciplinary
WOS记录号	WOS:000403565400001
引用统计	被引频次：54[WOS] [WOS记录] [WOS相关记录]
文献类型	期刊论文
条目标识符	http://ir.giec.ac.cn/handle/344007/14155
专题	中国科学院广州能源研究所
作者单位	1.Univ Sci & Technol China, Dept Thermal Sci & Energy Engn, Lab Basic Res Biomass Convers & Utilizat, Hefei 230026, Peoples R China 2.North Carolina State Univ, Dept Forest Biomat, Raleigh, NC 27695 USA 3.Chinese Acad Sci, Guangzhou Inst Energy Convers, CAS Key Lab Renewable Energy, Guangzhou 510640, Guangdong, Peoples R China
推荐引用方式 GB/T 7714	Zhu, Yuanshuai,Li, Wenzhi,Lu, Yijuan,et al. Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone[J]. RSC ADVANCES,2017,7(48):29916-29924.
APA	Zhu, Yuanshuai.,Li, Wenzhi.,Lu, Yijuan.,Zhang, Tingwei.,Jameel, Hasan.,...&Ma, Longlong.(2017).Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone.RSC ADVANCES,7(48),29916-29924.
MLA	Zhu, Yuanshuai,et al."Production of furfural from xylose and corn stover catalyzed by a novel porous carbon solid acid in gamma-valerolactone".RSC ADVANCES 7.48(2017):29916-29924.